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NOVEL IRIDIUM CATALYST COMPLEXES AND C-H BOND ACTIVATED PRODUCTS THEREFROM
NOVEL IRIDIUM CATALYST COMPLEXES AND C-H BOND ACTIVATED PRODUCTS THEREFROM
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机译:新型铱催化剂配合物和C-H键合活性产品
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摘要
Provided is a novel iridium catalyst complex which is useful in the dehydrogenation of alkanes. The iridium complex comprises the metal iridium atom complexed with a benzimidazolyl-containing ligand. The iridium atom can be coordinated with the nitrogen atoms in the benzimidazolyl-containing ligand to form an NCN pincer ligand complex. In another embodiment, the iridium catalyst is used, with or without a co-catalyst, in a dehydrogenation reaction converting alkanes to olefins. The reaction can be in a closed or open system, and can be run in a liquid or gaseous phase.
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