wherein M is a metal; A1 to A4 are independently of each other a substituent represented by general formula (2):        -D-E X-     (2)wherein D is a divalent organic group having 1 to 20 carbon atoms; E+ is a quaternary ammonium group or quaternary phosphonium group having 3 to 60 carbon atoms; and X is a halogen atom. There is thus provided a metalloporphyrin complex which, when used as a carbon dioxide fixation catalyst, exhibits high catalytic activity, has a small environmental burden and can be easily synthesized."/> METAL PORPHYRIN COMPLEX, METHOD FOR PRODUCING SAME, CARBON DIOXIDE IMMOBILIZATION CATALYST COMPRISING SAME, AND METHOD FOR PRODUCING CYCLIC CARBONIC ACID ESTER.
首页> 外国专利> METAL PORPHYRIN COMPLEX, METHOD FOR PRODUCING SAME, CARBON DIOXIDE IMMOBILIZATION CATALYST COMPRISING SAME, AND METHOD FOR PRODUCING CYCLIC CARBONIC ACID ESTER.

METAL PORPHYRIN COMPLEX, METHOD FOR PRODUCING SAME, CARBON DIOXIDE IMMOBILIZATION CATALYST COMPRISING SAME, AND METHOD FOR PRODUCING CYCLIC CARBONIC ACID ESTER.

机译:金属卟啉配合物,其制备方法,包含该化合物的二氧化碳固定化催化剂和环碳酸酯的制备方法。

摘要

There is provided a metalloporphyrin complex represented by general formula (1):wherein M is a metal; A1 to A4 are independently of each other a substituent represented by general formula (2):        -D-E X-     (2)wherein D is a divalent organic group having 1 to 20 carbon atoms; E+ is a quaternary ammonium group or quaternary phosphonium group having 3 to 60 carbon atoms; and X is a halogen atom. There is thus provided a metalloporphyrin complex which, when used as a carbon dioxide fixation catalyst, exhibits high catalytic activity, has a small environmental burden and can be easily synthesized.
机译:提供了由通式(1)表示的金属卟啉配合物: <图像文件=“ IMGA0001.GIF” he =“ 53” id =“ ia01” imgContent =“ chem” imgFormat =“ GIF” wi =“ 137” /> 其中M是金属; A 1 至A 4 彼此独立地是由通式(2)表示的取代基:-D-E X -(2)其中D是具有1至20个碳原子的二价有机基团; E + 是具有3至60个碳原子的季铵基团或季phospho基团; X是卤原子。因此,提供了一种金属卟啉配合物,当其用作二氧化碳固定催化剂时,其表现出高的催化活性,具有小的环境负担并且可以容易地合成。

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