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INTEGRAL SYNTHESIS GAS CONVERSION CATALYST EXTRUDATES AND METHODS FOR PREPARING AND USING SAME

机译:整体合成气转化催化剂挤出物及其制备和使用方法

摘要

Methods for preparing integral synthesis gas conversion catalyst extrudates including an oxide of a Fischer-Tropsch (FT) metal component and a zeolite component are disclosed. The oxide of the FT metal component is precipitated from a solution into crystallites having a particle size between about 2 nm and about 30 nm. The oxide of the FT metal component is combined with a zeolite powder and a binder material, and the combination is extruded to form integral catalyst extrudates. The oxide of the FT metal component in the resulting catalyst is in the form of reduced crystallites located outside the zeolite channels. No appreciable ion exchange of FT metal occurs within the zeolite channels. The acid site density of the integral catalyst extrudate is at least about 80% of the zeolite acid site density.
机译:公开了用于制备包括费-托(FT)金属组分的氧化物和沸石组分的整体合成气转化催化剂挤出物的方法。 FT金属组分的氧化物从溶液中沉淀到粒径为约2nm至约30nm的微晶中。将FT金属组分的氧化物与沸石粉末和粘合剂材料混合,并将该结合物挤出以形成整体催化剂挤出物。所得催化剂中FT金属组分的氧化物为位于沸石通道外部的还原微晶形式。在沸石通道内没有发生明显的FT金属离子交换。整体催化剂挤出物的酸位密度为沸石酸位密度的至少约80%。

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