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Zeolite with MRE structure and their analogue materials possessing mesopore, and synthesis method thereof

机译:具有中孔结构的具有mre结构的沸石及其类似物及其合成方法

摘要

The present invention relates to novel MRE zeolite and an analogous molecule material thereof, wherein the MRE zeolite is synthesized with a specially designed organic surfactant and has regularly or irregularly arranged mesopores of 2-50 nm that are formed by means of crystalline frames, each of which has a thickness of 5 nm or less; and to an organic assembly of the same. In addition, the present invention comprises a micro-mesoporous molecule material and a use of a catalyst thereof, wherein the micro-mesoporous molecule material is activated or functionalized by means of dealumination, ion exchange, and other post-treatment procedures. The novel materials have remarkably increased outside surface areas and pore volumes by means of the hierarchical combination structure of micro-pores and mesopores. Accordingly, molecule diffusion is enhanced so that activity is expected to be remarkably increased in the functions of catalysts and ion exchange resins that have been shown in existing zeolite.
机译:本发明涉及新颖的MRE沸石及其类似分子材料,其中MRE沸石是用专门设计的有机表面活性剂合成的,并具有规则或不规则排列的2-50nm的介孔,该介孔是通过晶格形成的,每个其厚度为5nm或更小;并进行相同的有机组装。另外,本发明包括微介孔分子材料及其催化剂的用途,其中所述微介孔分子材料通过脱铝,离子交换和其他后处理程序被活化或官能化。借助于微孔和中孔的分级组合结构,新材料显着增加了外表面积和孔体积。因此,提高了分子扩散,从而预期在现有沸石中显示的催化剂和离子交换树脂的功能中活性将显着提高。

著录项

  • 公开/公告号KR101451902B1

    专利类型

  • 公开/公告日2014-10-22

    原文格式PDF

  • 申请/专利权人

    申请/专利号KR20120134409

  • 发明设计人 유룡;김욱동;김정철;정윤재;

    申请日2012-11-26

  • 分类号B01J29/035;B01J2/08;C01B39/02;

  • 国家 KR

  • 入库时间 2022-08-21 15:39:54

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