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Photoluminescent POLYMER solar cells

机译:发光聚合物太阳能电池

摘要

1. A polymer solar cell, comprising sequentially: a carrier substrate made of transparent polymer photoluminescent substrate, a transparent anode layer; imetallichesky photoelectrically active layer of the cathode layer, wherein the photoluminescent polymer substrate consists of an optically transparent polymer containing a phosphor selected from the total number of luminophores formula (I), wherein R is a substituent from the group of linear or branched C1-C20 alkyl groups; linear or branched C1-C20 alkyl groups, separated by at least one oxygen atom; linear or branched C1-C20 alkyl groups, separated by at least one sulfur atom; branched C3-C20 alkyl groups, separated by at least one silicon atom; C2-C20 alkenyl groups; Ar is the same or different arylene or heteroarylene radicals selected from the group of substituted or unsubstituted thienyl-2,5-diyl, substituted or unsubstituted phenyl-1,4-diyl, substituted or unsubstituted 1,3-oxazol-2,5-diyl substituted fluoren-4,4-diyl, substituted cyclopentadithiophene-2,7-diyl; Q is a radical of the above series for Ar; X is at least one selected from said rows of Ar and / or a radical from the group of 2,1,3-benzotiodiazol-4,7-diyl, anthracene-9,10-diyl, 1,3,4-oxadiazole -2,5-diyl, 1-phenyl-2-pyrazoline-3,5-diyl, perylene-3,10-diyl; L is 1 or 3 or 7, preferably 1 or 3; n is an integer number from 2 to 4; m is an integer number from 1 to 3; k is an integer number from 1 to 3.2. Solar cell according to claim 1, characterized in that the phosphor is a phosphor of general formula (I), wherein R is hexyl, Ar and
机译:1。一种聚合物太阳能电池,其依次包括:由透明聚合物光致发光基底制成的载体基底;透明阳极层;和由所述聚合物基底构成的有机聚合物。阴极层的imetallichesky光电活性层,其中光致发光聚合物基材由光学透明的聚合物组成,该聚合物包含选自发光体式(I)的总数的荧光粉,其中R为直链或支链C1-C20的基团烷基;直链或支链的C1-C20烷基,被至少一个氧原子隔开;直链或支链的C1-C20烷基,被至少一个硫原子隔开;由至少一个硅原子隔开的支链C3-C20烷基; C 2 -C 20烯基; Ar为选自取代或未取代的噻吩基-2,5-二基,取代或未取代的苯基-1,4-二基,取代或未取代的1,3-恶唑-2,5-中的相同或不同的亚芳基或杂亚芳基。二基取代的芴-4,4-二基,取代的环戊二噻吩-2,7-二基; Q是上述Ar序列的一个基团; X是选自所述Ar行中的至少一个和/或选自2,1,3-苯并噻二唑-4,7-二基,蒽-9,10-二基,1,3,4-恶二唑的基团中的至少一个- 2,5-二基,1-苯基-2-吡唑啉-3,5-二基,per-3,10-二基; L为1或3或7,优选1或3; n是2至4的整数; m是1至3的整数; k是1到3.2之间的整数。 2.根据权利要求1所述的太阳能电池,其特征在于,所述荧光体是通式(I)的荧光体,其中R是己基,Ar和

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