R=4-C6H4-CH2-C6H4-4/, 4-C6H4-O-C6H4-4/, 4-H3COC6H3-C6H3OCH3-4/ which consists in the following: arylamines [diaminodiphenylmethane, diaminodiphenyloxide, dimethoxybenzidine] undergo interaction with N-tert-butyl-1,5,3-dithiazepinane in presence of catalyst Sm(NO3)3·6H2O in argon atmosphere with molar ratio arylamine:N-tert-butyl-1,5,3-dithiazeoinane: Sm(NO3)3·6H2O = 10 : 20 : (0.3-0.7) at temperature ~20°C in system of solvents ethanol-chloroform for 2.5-3.5 h.;EFFECT: increased efficiency of applying compound as antibacterial, antifungal and antiviral agents, biologically active complexants, selective sorbents and extractants of precious metals, special reagents for suppressing bacterial vital activity in different technical media.;1 tbl, 1 ex"/>
METHOD OF SELECTIVE OBTAINING 3,3'-METHYLENEBIS(1,4-PHENYLENE)-, 3,3'-OXYBIS(1,4-PHENYLENE)- AND 3,3'-(3,3'-DIMETHOXYBIPHENYL-4, 4'-DIYL)-BIS-1,5,3-DITHIAZEPINANES
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METHOD OF SELECTIVE OBTAINING 3,3'-METHYLENEBIS(1,4-PHENYLENE)-, 3,3'-OXYBIS(1,4-PHENYLENE)- AND 3,3'-(3,3'-DIMETHOXYBIPHENYL-4, 4'-DIYL)-BIS-1,5,3-DITHIAZEPINANES
METHOD OF SELECTIVE OBTAINING 3,3'-METHYLENEBIS(1,4-PHENYLENE)-, 3,3'-OXYBIS(1,4-PHENYLENE)- AND 3,3'-(3,3'-DIMETHOXYBIPHENYL-4, 4'-DIYL)-BIS-1,5,3-DITHIAZEPINANES
FIELD: chemistry.;SUBSTANCE: invention relates to organic chemistry, namely to method of obtaining 3,3'-[methylenebis(1,4-phenylene)]-, 3,3'-[oxybis(1,4-phenylene)]- and 3,3'-(3,3'-dimethoxybiphenyl-4, 4'-diyl)-bis-1,5,3-dithiazepinanes of general formula (1): R=4-C6H4-CH2-C6H4-4/, 4-C6H4-O-C6H4-4/, 4-H3COC6H3-C6H3OCH3-4/ which consists in the following: arylamines [diaminodiphenylmethane, diaminodiphenyloxide, dimethoxybenzidine] undergo interaction with N-tert-butyl-1,5,3-dithiazepinane in presence of catalyst Sm(NO3)3·6H2O in argon atmosphere with molar ratio arylamine:N-tert-butyl-1,5,3-dithiazeoinane: Sm(NO3)3·6H2O = 10 : 20 : (0.3-0.7) at temperature ~20°C in system of solvents ethanol-chloroform for 2.5-3.5 h.;EFFECT: increased efficiency of applying compound as antibacterial, antifungal and antiviral agents, biologically active complexants, selective sorbents and extractants of precious metals, special reagents for suppressing bacterial vital activity in different technical media.;1 tbl, 1 ex
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机译：技术领域本发明涉及有机化学，即涉及获得3,3'-[亚甲基双（1,4-亚苯基）]-，3,3'-[氧双（1,4-亚苯基）]的方法。 -和通式（1）的3,3'-（3,3'-二甲氧基联苯-4，4'-二基）-双-1,5,3-二硫杂pin烷： R = 4-C 6 H 4 -CH 2 -C 6 H 4 -4 /，4-C 6 H 4 -OC 6 H 4 -4 /，4-H 3 COC 6 H 3 -C < Sub> 6 H 3 OCH 3 -4 /由以下组成：芳胺[二氨基二苯甲烷，二氨基二苯醚，二甲氧基联苯胺]与N-叔丁基相互作用-1,5,3-二硫杂pin庚烷在催化剂Sm（NO 3 ） 3 ·6H 2 O的存在下，在氩气中，摩尔比为芳胺：N，叔丁基-1,5,3-二硫唑烷：Sm（NO 3 ） 3 ·6H 2 O = 10：20 ：s系统中在〜20°C的温度下为（0.3-0.7）在乙醇-氯仿中溶解2.5-3.5小时;效果：提高化合物作为抗菌剂，抗真菌剂和抗病毒剂，生物活性络合剂，贵金属的选择性吸附剂和萃取剂，在各种技术介质中抑制细菌生命活动的特殊试剂的使用效率。 ; 1 tbl，1 ex
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