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A method for producing propylene by simultaneous dehydration and skeletal isomerization of isobutanol over an acid catalyst followed by a metathesis step
A method for producing propylene by simultaneous dehydration and skeletal isomerization of isobutanol over an acid catalyst followed by a metathesis step
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机译:一种通过在酸催化剂上同时进行异丁醇的脱水和骨架异构化然后进行复分解步骤来生产丙烯的方法
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摘要
A process for production of propylene can include simultaneously subjecting isobutanol to dehydration and skeletal isomerization to make a mixture of n-butenes and iso-butene. The n-butenes can be subjected to methathesis. The process can include introducing isobutanol into a dehydration/isomerization reactor and contacting the isobutanol with a catalyst at conditions effective to dehydrate and skeletal isomerase the isobutanol to make a mixture of n-butenes and iso-butene. A mixture of n-butenes and iso-butene can be recovered and fractionated to produce an n-butenes stream. The n-butenes stream can be sent to a methathesis reactor and contacted with a catalyst at conditions effective to produce propylene. A stream can be recovered from the methathesis reactor that includes propylene, unreacted n-butenes, heavies, and optionally unreacted ethylene. The stream can be fractionated to recover propylene, and the unreacted n-butenes and unreacted ethylene can optionally be recycled to the methathesis reactor.
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