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4,4'-di-substituted 4H- cyclopentadithiophene and the new synthesis method

机译:4,4'-二取代的4H-环戊二噻吩及其合成新方法

摘要

PROBLEM TO BE SOLVED: To provide a new method for synthesizing 4, 4' disubstituted 4H-cyclopentadithiophene.;SOLUTION: There is provided a method for synthesizing a compound having general formula (I), including a step of reacting a compound (II) in the presence of a diprotic acid having a negative pKa, wherein R1 and R2 are organic groups; X and Y are independently selected from the group consisting of hydrogen, chlorine, bromine, iodine, boronic acid, boronate ester, borane, pseudohalogen and organotin. The method further relates to the compound (II) as a raw material and a compound to be obtained resulting from the ring closure of the compound (II).;COPYRIGHT: (C)2012,JPO&INPIT
机译:解决的问题:提供一种合成4,4'二取代的4H-环戊二噻吩的新方法。解决方案:提供一种合成具有通式(I)的化合物的方法,包括使化合物(II)反应的步骤在具有pKa为负的二质子酸的存在下,其中R 1 和R 2 是有机基团; X和Y独立地选自氢,氯,溴,碘,硼酸,硼酸酯,硼烷,假卤素和有机锡。该方法还涉及作为原料的化合物(II)和由化合物(II)的闭环得到的化合物。;版权所有:(C)2012,JPO&INPIT

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