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Method for producing electrode catalyst fine catalyst particle, and method for producing carbon supported catalyst fine particle for electrode catalyst

机译:电极催化剂微粒催化剂粒子的制造方法及电极催化剂用碳担载催化剂微粒的制造方法

摘要

PROBLEM TO BE SOLVED: To provide a method for producing catalyst fine particles having excellent catalytic activity, and a method for producing carbon-supported catalyst fine particles.SOLUTION: The method for producing the catalyst fine particles each having an inner fine particle and an outermost layer containing platinum and covering the inner fine particle includes processes for preparing a reversed micelle dispersion liquid containing fine particles comprising a first metal oxide without an oxygen defect, and preparing a reversed micelle dispersion liquid containing platinum ions, and a reduction process for mixing at least the reversed micelle dispersion liquid containing fine particles comprising the first metal oxide, the reversed micelle dispersion liquid containing the platinum ions, and a sacrificial agent, and irradiating the mixture with microwaves to reduce at least the surface of the fine particle comprising the first metal oxide, into a second metal oxide with an oxygen defect and to form, on the second metal oxide, the outermost layer containing platinum formed by reducing the platinum ions.
机译:解决的问题:提供一种制备具有优异催化活性的催化剂细颗粒的方法,以及一种制备碳负载的催化剂细颗粒的方法。包含铂并覆盖内部细颗粒的层包括以下步骤:制备包含无氧缺陷的包含第一金属氧化物的细颗粒的反胶束分散液,以及制备包含铂离子的反胶束分散液,以及至少混合的还原方法。包含含有第一金属氧化物的微粒的反相胶束分散液,包含铂离子和牺牲剂的反相胶束分散液,并用微波照射混合物以至少还原包含第一金属氧化物的微粒的表面,与氧气混合成第二种金属氧化物缺陷并在第二金属氧化物上形成最外层,该最外层包含通过还原铂离子而形成的铂。

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