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Hydrogen storage alloy for alkaline storage battery, and alkaline storage battery and alkaline storage battery system each including negative electrode having the alloy

机译:用于碱性蓄电池的储氢合金,以及碱性蓄电池和碱性蓄电池系统,每个包括具有该合金的负极

摘要

To provide a hydrogen storage alloy for an alkaline storage battery that improves output power by pulverization of the alloy in the initial stage of partial charge and discharge cycles and that maintains its surface condition to improve the amount of lifetime work (Wh), and an alkaline storage battery and battery system. A hydrogen storage alloy for an alkaline storage battery includes a composition expressed by LaxReyMg1-x-yNin-m-vAlmTv (Re: rare earth element(s) including Y; T: Co, Mn, Zn; 0.17≦x≦0.64, 3.5≦n≦3.8, 0.06≦m≦0.22, v≧0), and a main phase of an A5B19 type crystal structure. A ratio of X/Y of the concentration ratio X of Al to Ni in a surface layer and the concentration ratio Y of Al to Ni in a bulk layer is 0.36≦X/Y≦0.85. An alkaline storage battery includes the hydrogen storage alloy in its negative electrode. An alkaline storage battery system performs partial charge and discharge control.
机译:提供一种用于碱性蓄电池的储氢合金,该储氢合金通过在部分充放电循环的初始阶段将其粉化来提高输出功率,并保持其表面状态以改善使用寿命(Wh),并提供一种碱性蓄电池和电池系统。用于碱性蓄电池的储氢合金包括由La x Re y Mg 1-xy Ni nmv 表示的组成Sub> Al m T v (Re:包括Y的稀土元素; T:Co,Mn,Zn; 0.17≦x≦0.64,3.5≦n≦ 3.8、0.06≤m≤0.22,v≥0)和A 5 B 19 型晶体结构的主相。表面层中Al与Ni的浓度比X与块状层中Al与Ni的浓度比Y的X / Y之比为0.36≤X/Y≤0.85。碱性蓄电池在其负极中包括储氢合金。碱性蓄电池系统执行部分充电和放电控制。

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