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Method of preparing a transparent polymer material comprising a thermoplastic polycarbonate and surface-modified mineral nanoparticles

机译:制备包含热塑性聚碳酸酯和表面改性的矿物纳米粒子的透明聚合物材料的方法

摘要

A method of preparing a transparent polymer material includes i) obtaining composite nanoparticles having mineral nanoparticles at least partially coated with at least one monomer and/or at least one polymer suitable for promoting physicochemical interactions at the interface between the mineral nanoparticles and a thermoplastic polycarbonate matrix, the mineral nanoparticles being surface-modified by the monomer and/or the polymer, either directly by grafting or directly by adsorption of the monomer and/or polymer onto the surface of the mineral nanoparticles; or via a coupling agent selected from a chlorosilane or an organosilane including a functional group that is capable of reacting by a radical pathway. The composite nanoparticles obtained in step i) are mixed with the thermoplastic polycarbonate matrix in the molten state to obtain the transparent polymer material.
机译:一种制备透明聚合物材料的方法,包括:i)获得具有至少部分地涂覆有至少一种单体和/或至少一种聚合物的矿物纳米颗粒的复合纳米颗粒,所述矿物纳米颗粒适于促进矿物纳米颗粒与热塑性聚碳酸酯基质之间的界面处的物理化学相互作用。 ,通过单体和/或聚合物直接或通过接枝或直接通过将单体和/或聚合物吸附到矿物纳米颗粒的表面上,将矿物纳米颗粒表面改性;或通过选自包括能够通过自由基途径反应的官能团的氯硅烷或有机硅烷的偶联剂。将步骤i)中获得的复合纳米颗粒与热塑性聚碳酸酯基体在熔融状态下混合以获得透明聚合物材料。

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