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Production methods for solubilized lignin, saccharide raw material and monosaccharide raw material, and solubilized lignin

机译:可溶性木质素,糖原料和单糖原料以及可溶性木质素的生产方法

摘要

A new lignin degradation product, a method for producing the same, and methods for producing a saccharide raw material and a monosaccharide raw material are provided.;The method for producing the new lignin degradation product includes: (a first step) mixing 100 parts by mass of a powder, obtained by pulverizing a lignocellulosic raw material and defatting the resulting powder with an organic solvent, with aqueous hydrogen peroxide in an amount of 20 to 400 parts by mass in terms of hydrogen peroxide and heating the mixture for 5 to 120 minutes at a pressure of 0.1 to 1.5 MPa and a temperature of 80 to 200° C. while irradiating the mixture with microwaves; (a second step) separating insoluble matter from the aqueous hydrogen peroxide; (a third step) extracting the insoluble matter with a solvent to produce an extract; and (a fourth step) distilling the solvent away from the extract to yield a solubilized lignin as a residue. Further, a saccharide raw material composed mainly of a polysaccharide or a monosaccharide raw material is obtained by subjecting the liquid portion or the insoluble matter, respectively, obtained in the first step to a predetermined treatment.
机译:提供了一种新的木质素降解产物,其制备方法以及糖类原料和单糖原料的制备方法。所述新的木质素降解产物的制备方法包括:(第一步)混合100份通过将木质纤维素原料粉碎并用有机溶剂对所得粉末脱脂,并以过氧化氢换算为20至400质量份的过氧化氢水溶液并将混合物加热5至120分钟而获得在用微波照射混合物的同时,在0.1至1.5MPa的压力和80至200℃的温度下; (第二步骤)从过氧化氢水溶液中分离出不溶物; (第三步骤)用溶剂萃取不溶物以产生萃取物; (第四步骤)从提取物中蒸馏出溶剂,得到溶解的木质素残余物。此外,通过对在第一步骤中获得的液体部分或不溶物分别进行预定处理,从而获得主要由多糖或单糖原料组成的糖原料。

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