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Non-flammable quasi-solid electrolyte and non-lithium alkali metal or alkali-ion secondary batteries containing same
Non-flammable quasi-solid electrolyte and non-lithium alkali metal or alkali-ion secondary batteries containing same
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机译:不可燃的准固体电解质和包含其的非锂碱金属或碱金属离子二次电池
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摘要
A non-flammable quasi-solid electrolyte and a rechargeable non-lithium alkali metal cell containing this electrolyte. The electrolyte comprises an alkali metal salt dissolved in an organic liquid solvent with a concentration higher than 2.5 M (preferably 3.5 M) or a molecular ratio greater than 0.2 (preferably 0.3), wherein the alkali metal is selected from Na, K, a combination of Na and K, or a combination of Na and/or K with Li. The alkali metal salt concentration is sufficiently high so that the electrolyte exhibits a vapor pressure 0.01 kPa when measured at 20° C., a vapor pressure 60% of the vapor pressure of thet organic solvent when measured alone, a flash point at least 20 degrees Celsius higher than a flash point of the organic liquid solvent when measured alone, a flash point higher than 150° C., or no detectable flash point.
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