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Method for doping and dedoping lithium into and from negative electrode and method for producing negative electrode for lithium secondary battery

机译:将锂掺杂到负极中和从负极去掺杂锂的方法以及锂二次电池负极的制造方法

摘要

The object of an exemplary embodiment of the invention is to provide a negative electrode having excellent cycle property. An exemplary embodiment of the invention a method for doping and dedoping lithium for the first time after a negative electrode for a lithium secondary battery comprising silicon oxide as an active material is produced, comprising doping the lithium within the following current value range (A) and within the following doped amount range (B); current value range (A): a range of a current value in which a doped amount in which only one peak appears at 1 V or less on the V-dQ/dV curve becomes maximum, wherein the V-dQ/dV curve represents a relationship between voltage V of the negative electrode with respect to a lithium reference electrode and dQ/dV that is a ratio of variation dQ of lithium dedoped amount Q in the negative electrode to variation dV of the voltage V, and doped amount range (B): a range of a doped amount in which only one peak appears at 1 V or less on the V-dQ/dV curve.
机译:本发明的示例性实施方式的目的是提供一种具有优异循环特性的负极。在本发明的示例性实施方式中,提供了一种在生产包含氧化硅作为活性材料的锂二次电池用负极之后,对锂进行第一次掺杂和去掺杂的方法,该方法包括在以下电流值范围(A)中掺杂锂。在以下掺杂量范围内(B);电流值范围(A):其中在V-dQ / dV曲线上仅在1V以下出现一个峰的掺杂量最大的电流值范围,其中,V-dQ / dV曲线表示负极相对于锂参比电极的电压V与dQ / dV之间的关系,其为负极中锂去掺杂量Q的变化量dQ与电压V的变化量dV之比,以及掺杂量范围(B) :在V-dQ / dV曲线上在1 V或更低时仅出现一个峰值的掺杂量范围。

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