Controlled radical copolymerization of fluorinated monomers by xanthate or trithiocarbonate

摘要

The invention relates to a method of preparing a fluorinated copolymer, comprising a step of copolymerization of a fluorinated monomer (of the vinylidene fluoride type) with an α-trifluoromethacrylic acid monomer or derivative of α-trifluoromethacrylic acid, in the presence of a xanthate or trithiocarbonate compound. The invention also relates to copolymers obtained by this method as well as block copolymers comprising a copolymer block prepared according to this method.