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Catalyst system, process for the carbonylation of an ethylenically unsaturated compound, reaction medium, use of a system, and complex

机译:催化剂体系,烯键式不饱和化合物羰基化的方法,反应介质,体系的用途和配合物

摘要

The present invention provides a catalyst system capable of catalysing the carbonylation of an ethylenically unsaturated compound, which system is obtainable by combining: a) a metal of Group VIB or Group VIIIB or a compound thereof, b) a bidentate phosphine, arsine or stibine ligand, and c) an acid, wherein said ligand is present in at least a 2:1 molar excess compared to said metal or said metal in said metal compound, and that said acid is present in at least a 2:1 molar excess compared to said ligand, a process for the carbonylation of an ethylenically unsaturated compound, a reaction medium, and use of the system.
机译:本发明提供了一种能够催化烯键式不饱和化合物羰基化的催化剂体系,该体系可通过组合以下方法获得:a)第VIB族或第VIIIB族的金属或其化合物,b)二齿膦,a或锑的配体,和c)酸,其中所述配体与所述金属或所述金属化合物中的所述金属相比以至少2:1摩尔过量存在,并且所述酸与所述配体相比以至少2:1摩尔过量存在。烯键式不饱和化合物的羰基化,反应介质和该系统的用途。

著录项

  • 公开/公告号BRPI0507805B1

    专利类型

  • 公开/公告日2015-06-23

    原文格式PDF

  • 申请/专利权人 LUCITE INTERNATIONAL UK LIMITED;

    申请/专利号BR2005PI07805

  • 发明设计人 GRAHAM EASTHAM;NEIL TINDALE;

    申请日2005-02-17

  • 分类号B01J31/24;C07C51/14;C07C67/38;

  • 国家 BR

  • 入库时间 2022-08-21 15:16:14

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