首页> 外国专利> SELECTIVE HYDRODESULPHURIZATION OF GASOLINE LIQUID CATALYTIC CRACKING BEFORE SULFUR CONTENT LESS THAN 10 CH / MILLION

SELECTIVE HYDRODESULPHURIZATION OF GASOLINE LIQUID CATALYTIC CRACKING BEFORE SULFUR CONTENT LESS THAN 10 CH / MILLION

机译:硫含量低于10百万/百万之前汽油液相催化裂解选择性加氢脱硫。

摘要

A method is described for reducing the sulfur content in a hydrocarbon stream. Cracked naphtha full fraction is brought into contact with a hydrogenation catalyst to convert at least part of the dienes and mercaptans to thioethers and to hydrogenate at least part of the dienes. Full-fraction cracked naphtha is divided into a light naphtha fraction, a middle naphtha fraction, and a heavy naphtha fraction. The heavy naphtha fraction is hydrodesulphurized. The middle fraction of naphtha is mixed with hydrogen and gas oil to form a mixture, which is brought into contact with a hydrodesulfurization catalyst, to obtain an average fraction of naphtha having a lower sulfur concentration. In some embodiments, the light, heavy, and medium naphtha fractions can then be recombined to form a hydrodesulfurized product having a sulfur content of less than 10 ppm.
机译:描述了一种减少烃流中硫含量的方法。使裂化的石脑油全部馏分与氢化催化剂接触,以将至少部分的二烯和硫醇转化为硫醚并氢化至少部分的二烯。全馏分裂化石脑油分为轻石脑油馏分,中石脑油馏分和重石脑油馏分。重的石脑油馏分被加氢脱硫。将石脑油的中间馏分与氢气和粗柴油混合以形成混合物,使其与加氢脱硫催化剂接触,以获得具有较低硫浓度的石脑油的平均馏分。在一些实施方案中,轻,重和中度石脑油馏分然后可以重新组合以形成硫含量小于10ppm的加氢脱硫产物。

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