首页> 外国专利> A PROCESS FOR SEPARATING AROMATICS AND REMOVAL OF SULPHUR COMPOUNDS FROM HRART CUT OF CATALYTICALLY CRACKED GASOLINE

A PROCESS FOR SEPARATING AROMATICS AND REMOVAL OF SULPHUR COMPOUNDS FROM HRART CUT OF CATALYTICALLY CRACKED GASOLINE

机译:从裂解裂口汽油的HRART馏分中分离芳香族化合物和脱除硫化合物的方法

摘要

The present invention provide an improved extractive distillation (ED) process wherein a hydrocarbon feed containing a mixture of aromatics, olefinic, diolefinic and other non¬aromatic hydrocarbons along with impurities like chloride and oxygenates i.e. stream of catalytically cracked gasoline is contacted with an aromatics selective solvent mixture comprising NMP based solvent in admixture with additives as extraction solvent in an ED column to produce an aromatics rich bottom (extract hydrocarbons) and an aromatics lean raffinate hydrocarbons with ultra low sulfur gasoline (ULSG). The solvent mixture is added to the top of the ED column and the feed mixture is added at a point on the ED column that is lower than the point where the solvent mixture is added. Extractive distillation is performed, and the aromatic and non-aromatic hydrocarbons are separated. Accordingly in the present invention the di- olefins present in the said feedstock i.e. catalytically cracked gasoline plays a very important role and leads to gum formation with most of the solvents except the solvent mentioned in the present invention.
机译:本发明提供了一种改进的萃取蒸馏(ED)方法,其中使包含芳族化合物,烯烃,二烯烃和其他非芳族烃以及诸如氯化物和含氧化合物的杂质的混合物的烃进料,即催化裂化的汽油流与选择性芳族化合物接触。溶剂混合物,其中包含NMP基溶剂与作为萃取溶剂的添加剂在ED色谱柱中的混合物,以与超低硫汽油(ULSG)一起生产富芳烃的塔底馏出物(萃取烃)和贫芳烃的萃余烃。将溶剂混合物添加到ED塔的顶部,并且将进料混合物添加到ED柱上的一个点,该点低于添加溶剂混合物的点。进行萃取蒸馏,并分离芳族和非芳族烃。因此,在本发明中,存在于所述原料中的二烯烃,即催化裂化的汽油起着非常重要的作用,并导致除了本发明中提到的溶剂以外的大多数溶剂形成胶。

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