首页> 外国专利> 4-(E)-4-bis(2-hydroxyethyl)aminophenyl)azo-N-(4,6-dimethylpyrimidin-2-yl)benzenosulfonamid and method for producing it

4-(E)-4-bis(2-hydroxyethyl)aminophenyl)azo-N-(4,6-dimethylpyrimidin-2-yl)benzenosulfonamid and method for producing it

机译:4-[(E)-[4- [双(2-羟乙基)氨基苯基)偶氮] -N-(4,6-二甲基嘧啶-2-基)苯磺酰胺及其制备方法

摘要

the invention discloses 4 - [(e) - [4 - [bis (2 - hydroxyethyl) amino] phenyl] azo] - n - (4,6 - dimetylopirymidyn - 2 - yl) benzenosulfonoamid model 1 is applicable in nonlinear optics, optoelektronice as material modifying properties under the influence of light and to obtain monomer, polymer s and hybrid materials properties fotochromowych modifying properties under the influence of light.they may be used in the optical information processing and.also revealed way to produce 4 - [(e) - [4 - [bis (2 - hydroxyethyl) amino] phenyl] azo] - n - (4,6 - dimetylopirymidyn - 2 - yl) benzenosulfonoamidu of model 1 that a 4 - amino - n - (4,6 - dimetylopirymidyn - 2 - yl) benzenesulfonamide shall be subjected to the reaction diazowania nitrate (iii) in a mixture of sodium s tu0119u017conego hydrochloric acid, water and glacial acetic acid.and then the resulting salt diazoniowu0105 4 - amino - n - (4,6 - dimetylopirymidyn - 2 - yl) benzenesulfonamide hydrochloride in the form of chloride are coupled together with aniline which is bis (n - (2 - hydroxyethyl) aniline in a ratio of 1: 1 to 1: 1.3, while the reaction diazowania leads in a mixture of concentrated hydrochloric acid.water and glacial acetic acid containing from 6 to 10% by volume of concentrated hydrochloric acid and from 50 to 60% glacial acetic acid, and then the resulting product neutralises, drought and clears.
机译:本发明公开了4-[(e)-[4- [双(2-羟乙基)氨基]苯基]偶氮] -n-(4,6-二甲吡喃并咪唑-2-基)苯甲磺酰胺模型1适用于非线性光学,光电电子作为受光影响的材料改性性能,并获得单体,聚合物和杂化材料的性能。受光影响的染料变色性能。它们可用于光学信息处理,并且还揭示了制备4-[[e )-[4-(双(2-羟乙基)氨基]苯基]偶氮]-[4- [双-(2-羟乙基)氨基]苯基]偶氮]-[4-[-(4-(2-羟乙基)氨基)苯基]偶氮] [2-yyl)苯甲磺酰胺基-2-yl)苯磺酰胺应在碳酸氢钠,水和冰醋酸的混合物中与硝酸重氮钾(iii)反应,然后将所得的重氮唑鎓盐(u2105)4-氨基-n-氯化物形式的(4,6-二甲吡喃并咪唑-2-基)苯磺酰胺盐酸盐苯胺与双(n-(2-羟乙基)苯胺的苯胺以1:1至1:1.3的比例偶联在一起,而反应重氮基导致的是浓盐酸,水和冰醋酸的混合物,其中含有6至按体积计10%的浓盐酸和50%至60%的冰醋酸,然后中和,中和,干燥。

著录项

  • 公开/公告号PL410592A1

    专利类型

  • 公开/公告日2015-09-14

    原文格式PDF

  • 申请/专利权人 POLITECHNIKA WROCŁAWSKA;

    申请/专利号PL20140410592

  • 发明设计人 EWELINA ORTYL;SONIA ZIELIŃSKA;

    申请日2014-12-19

  • 分类号C07D239/69;

  • 国家 PL

  • 入库时间 2022-08-21 15:13:19

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