首页> 外国专利> 4-(E)-(4-bis(N-methyl)aminophenyl)azo-N-(4,6-dimethylpyrimidin-2-yl)benzenosulfonamid and method for producing it

4-(E)-(4-bis(N-methyl)aminophenyl)azo-N-(4,6-dimethylpyrimidin-2-yl)benzenosulfonamid and method for producing it

机译:4-[(E)-(4-双(N-甲基)氨基苯基)偶氮] -N-(4,6-二甲基嘧啶-2-基)苯磺酰胺及其制备方法

摘要

the invention relates to 4 - [(e) - (4 - bis (n - methyl) aminophenyl) azo] - n - (4,6 - dimetylopirymidyn - 2 - yl) benzenosulfonoamidu of model 1, which is applicable to nonlinear optics, optoelektronice as material modifying properties under the influence of light and to obtain hybrid materials and polymeric systems type "guest host" properties fotochromowych,changing under the influence of light. they may be used in the optical information processing and.the invention also discloses method of 4 - [(e) - (4 - bis (n - methyl) aminophenyl) azo] - n - (4,6 - dimetylopirymidyn - 2 - yl) benzenosulfonoamidu of model 1 that a 4 - amino - n - (4,6 - dimetylopirymidyn - 2 - yl) benzenesulfonamide subjected the reaction diazowania nitrate (iii) sodium mixture st u0119u017conego hydrochloric acidwater and glacial acetic acid from 6 to 10% by volume of concentrated hydrochloric acid and from 50 to 60% glacial acetic acid, and then the salt diazoniowu0105 4 - amino - n - (4,6 - dimetylopirymidyn - 2 - yl) benzenesulfonamide hydrochloride in the form of chloride are coupled together with aniline which is bis (n - methyl) and nilinu0105 at mole ratio in the range of 1: 1 to 1: 1.3, then the product obtained neutralises,drought and clears.
机译:本发明涉及模型1的4-[[(e)-(4-双(n-甲基)氨基苯基)偶氮] -n-(4,6-二metylopirymidyn-2-2-基)苯甲磺酰胺基,其适用于非线性光学,光电子学作为材料在光的作用下改变性质,并获得杂化材料和聚合物系统类型的“客体”性质,在光的作用下发生变化。它们也可以用于光学信息处理中。本发明还公开了4-[(e)-(4-双(n-甲基)氨基苯基)偶氮] -n-(4,6-二metylopirymidyn-2-2-基的方法。 )模型1的苯甲磺酰胺基,其中4-氨基-正-(4,6-二甲吡喃并咪唑-2-基)苯磺酰胺反应发生了硝酸重氮wan(iii)钠混合物st u0119 u017conego盐酸水和冰醋酸从6到10将50%(体积)的浓盐酸和50%至60%的冰醋酸,然后以氯化物形式偶合盐二氮杂oni 4-氨基-n-(4,6-二甲吡喃并咪唑-2-基)苯磺酰胺盐酸盐与摩尔比为1:1至1:1.3的双(n-甲基)苯胺和nilin u105一起,所得产物中和,变干和澄清。

著录项

  • 公开/公告号PL410594A1

    专利类型

  • 公开/公告日2015-09-14

    原文格式PDF

  • 申请/专利权人 POLITECHNIKA WROCŁAWSKA;

    申请/专利号PL20140410594

  • 发明设计人 EWELINA ORTYL;SONIA ZIELIŃSKA;

    申请日2014-12-19

  • 分类号C07D239/69;

  • 国家 PL

  • 入库时间 2022-08-21 15:13:19

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