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Process for polymerizing olefin-based polymers containing high molecular weight fractions in condensed mode and super-condensed

机译:用于以冷凝模式和超冷凝方式聚合包含高分子量馏分的烯烃基聚合物的方法

摘要

A process for producing a polymer of an olefin basis which comprises polymerizing, in a polymerization reactor that includes a fluidized bed a disengaging zone and a neck connecting the bed and the disengagement zone, at least one monomer in the gas phase, in the presence of at least the following components: A) at least one catalyst containing at least two transition metals one of which is Ti; B) at least one cocatalyst; C) a composition comprising at least one compound selected from those of formula (I) and / or at least one compound selected from those of formula (II); where (R1CO2) 2AlOH (I) = formula (I), (R2) xN (R3OH) y = formula (II), R1 is a hydrocarbon radical having 13 to 25 carbon atoms, R2 is a hydrocarbon radical having from 14 to 26 carbon atoms, R3 is a hydrocarbon radical having 1 to 4 carbon atoms; x + y = 3 and x has a value of 1 or 2; and wherein further the reactor is operated in condensed mode and the average height of the fluidized bed is maintained above the neck of the polymerization reactor.
机译:一种生产基于烯烃的聚合物的方法,该方法包括在以下条件下在气相中使至少一种单体在包括流化床的聚合反应器中聚合至少一个单体在气相流化床中进行连接。至少以下成分:A)至少一种催化剂,其包含至少两种过渡金属,其中一种为Ti。 B)至少一种助催化剂; C)一种组合物,其包含至少一种选自式(I)的化合物和/或至少一种选自式(II)的化合物;其中(R1CO2)2AlOH(I)> =式(I),(R2)xN(R3OH)y> =式(II),R1是具有13至25个碳原子的烃基,R2是具有14个碳原子的烃基R 3为碳原子数为26的碳原子数为1至4的烃基。 x + y> = 3且x的值为1或2;并且其中反应器进一步以冷凝模式操作,并且流化床的平均高度保持在聚合反应器的颈部上方。

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