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aromatic monomers derived from glycerol units, process for their preparation and use thereof for the preparation of water-soluble conjugated polymers

机译:衍生自甘油单元的芳族单体,其制备方法及其在制备水溶性共轭聚合物中的用途

摘要

Monomers having the following general structure (I): Formula ** ** in which: - Ar is a C6-C12 aromatic radical, a C12-C18 polycyclic aromatic radical, or Ar is a heteroaromatic radical containing one or more heteroatoms such as S, N, Se, O, optionally polycondensates, - X is a group which can be polymerized by a reaction selected from the reactions of Suzuki, Stille, Heck or Yamamoto, which is selected from -Br, -Cl, - I, -O- (SO2) -CF3, -B (OH) 2, -B (OR ') 2, -SnR'3, -B (OR''O) and vinyl, R' being a radical C1- C6 and R '' an ethylene radical, optionally substituted with alkyl C1-C2; R1 and R2, identical or different, may be a hydrogen atom or C1-C6 alkyl radical; - R is an alkylene radical C1-C12 divalent; - n is between 1 and 4.
机译:具有以下通式(I)的单体:式** **其中:-Ar是C6-C12芳族基团,C12-C18多环芳族基团,或Ar是包含一个或多个杂原子(例如S)的杂芳族基团,N,Se,O,任选的缩聚物,-X是可以通过选自Suzuki,Stille,Heck或Yamamoto的反应聚合的基团,所述反应选自-Br,-Cl,-I,-O -(SO2)-CF3,-B(OH)2,-B(OR')2,-SnR'3,-B(OR''O)和乙烯基,R'是基团C1-C6和R''任选地被烷基C 1 -C 2取代的亚乙基; R1和R2相同或不同,可以是氢原子或C1-C6烷基。 -R为亚烷基C1-C12二价; -n在1到4之间。

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