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METHOD FOR PREPARING NANO METAL/METAL OXIDE LOADED MOLECULAR SIEVE CATALYST

机译:纳米金属/金属氧化物负载的分子筛催化剂的制备方法

摘要

A method for preparing nano metal/metal oxide loaded molecular sieve catalyst. A nonpolar organic solvent is used as a continuous phase, and a water solution of metal salt and a water-soluble organic carbon source is used as a dispersed phase; and a surfactant is added to form a water-in-oil type micro emulsion system, so as to continually accelerate carbonization of the organic carbon source through azeotropic distilled water removing at a high temperature to obtain carbon-covered metal oxide nano particles with a uniform size and a nuclear shell structure; the carbon-covered metal oxide nano particles washed by using an organic solvent and water are dispersed in a molecular sieve precursor mixed solution, the molecular sieve on which carbon-covered metal oxide nano particles are uniformly distributed are obtained by using a hydrothermal synthesis; and calcination is performed, or reduction is performed after calcination to obtain a nano metal/alloy loaded molecular sieve catalyst.
机译:一种制备纳米金属/金属氧化物负载分子筛催化剂的方法。非极性有机溶剂用作连续相,金属盐和水溶性有机碳源的水溶液用作分散相。加入表面活性剂形成油包水型微乳液体系,通过高温下共沸蒸馏水去除有机碳源,持续加速有机碳源的碳化,从而得到均匀的碳被覆金属氧化物纳米颗粒。大小和核壳结构;将有机溶剂和水洗涤后的碳覆盖的金属氧化物纳米颗粒分散在分子筛前驱体混合溶液中,通过水热合成得到均匀分布碳覆盖的金属氧化物纳米颗粒的分子筛。然后进行煅烧,或者在煅烧后进行还原,得到纳米金属/合金负载分子筛催化剂。

著录项

  • 公开/公告号WO2014190681A1

    专利类型

  • 公开/公告日2014-12-04

    原文格式PDF

  • 申请/专利权人 CHANGZHOU UNIVERSITY;

    申请/专利号WO2013CN87202

  • 申请日2013-11-15

  • 分类号B01J37/00;B01J29/42;B01J29/48;B01J29/61;B01J29/64;B01J29/72;B01J29/78;B01J29/85;B01J29/89;

  • 国家 WO

  • 入库时间 2022-08-21 15:09:55

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