POLYACRYLONITRILE POLYMER, PROCESS FOR PRODUCTION OF THE POLYMER, PROCESS FOR PRODUCTION OF PRECURSOR FIBER FOR CARBON FIBER, CARBON FIBER, AND PROCESS FOR PRODUCTION OF THE CARBON FIBER

摘要

A polyacrylonitrile-based polymer, containing a polymer of which main component is acrylonitrile, which satisfies at least one kind requirement selected from the following [a] to [d].[a] Z-average molecular weight (Mz) determined by gel-permeation chromatograph is 800,000 to 6,000,000 and degree of polydispersity (Mz/Mw) (Mw denotes weight average molecular weight) is 3.0 to 10.0.[b] Z+1-average molecular weight (Mz+1) determined by GPC method is 3,000,000 to 10,000,000 and degree of polydispersity (Mz+1/Mw) is 6.0 to 25.0.[c] Mzm determined by gel-permeation chromatograph[space]multi-angle laserlight scattering photometry is 400,000 to 1,000,000 and degree of polydispersity (Mzm/Mwm) is 3.0 to 10.0.[d] Z-average radius of gyration (Rz) determined by gel-permeation chromatograph[space]multi-angle laserlight scattering photometry is 25 to 45 nm and its ratio to weight average radius of gyration (Rz/Rw) is 1.3 to 2.5.