首页> 外国专利> METHOD OF PRODUCTION OF A MATERIAL WITH PHOTOCATALYTIC AND BIOCIDAL PROPERTIES CONTAINING SPATIALLY ORIENTED TITANIUM DIOXIDE NANOTUBES MODIFIED WITH METALS, PARTICULARLY PRECIOUS METALS

METHOD OF PRODUCTION OF A MATERIAL WITH PHOTOCATALYTIC AND BIOCIDAL PROPERTIES CONTAINING SPATIALLY ORIENTED TITANIUM DIOXIDE NANOTUBES MODIFIED WITH METALS, PARTICULARLY PRECIOUS METALS

机译:具有光催化和生物杀菌性质的材料的制造方法,该材料包含金属,尤其是贵金属改性的空间取向的二氧化钛纳米管

摘要

Method of production of a material with photocatalytic and biocidal properties containing spatially oriented titanium dioxide nanotubes modified with metals, particularly precious metals. The method of production of a material with photocatalytic and biocidal properties containing spatially oriented titanium dioxide nanotubes modified with metals, particularly precious metals, consisting in being subjected to induced electric current placed in an electrolyte containing ammonium fluoride and ethylene glycol of the base containing titanium, preferably titanium foil, cleaning the obtained material with ultrasounds and then drying and calcinating is characterised according to the invention by the fact that the received material is placed in a multi-component solution, preferably in the neutral gas atmosphere. A multi-component solution must contain 30-50% of alcohol by weight, preferably isopropanol, as well as ions and/or nanomolecules of one or several metals, preferably two or three, selected from the groups including silver, gold, platinum, palladium, ruthenium, copper, zinc, nickel, rhodium, tungsten, cobalt, iron in the amount of 0.05 - 5% of the weight each as well as water. The mutual weight ratio of the metals is determined to be between 1: 1 and 1: 10. Preferably the multi-component solution is mixed in darkroom conditions for 3-180 min, preferably 120 min. Next, it is irradiated with an UV-emitting lamps for 0.5-6 hrs, dried at the temperature of 60 - 100° C for 0.5 - 24 hrs, favourably for 6 -12 hrs.
机译:具有光催化和杀生物特性的材料的生产方法,该材料包含用金属特别是贵金属改性的空间取向的二氧化钛纳米管。一种具有光催化和杀生物特性的材料的制造方法,该材料包含用金属特别是贵金属改性的空间取向的二氧化钛纳米管,该方法包括在置于含氟化铵的电解质和含钛碱的乙二醇中施加感应电流,根据本发明,优选将优选的材料优选为钛箔,用超声波清洗所获得的材料,然后干燥并煅烧,其特征在于,将所接收的材料置于多组分溶液中,优选在中性气体气氛中。多组分溶液必须包含按重量计30%至50%的醇,优选异丙醇,以及选自包括银,金,铂,钯的一种或几种金属(优选为两种或三种)的离子和/或纳米分子含量分别为重量的0.05-5%的钌,铜,锌,镍,铑,钨,钴,铁以及水。确定金属的相互重量比在1:1和1:10之间。优选地,将多组分溶液在暗室条件下混合3-180分钟,优选120分钟。接下来,用发射紫外线的灯照射0.5-6小时,在60-100℃的温度下干燥0.5-24小时,优选6-12小时。

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