首页> 外国专利> HYDROGEN SENSOR BASED ON NICKEL/PALLADIUM-GRAPHENE NANOCOMPOSITE AND METHOD OF FABRICATING THE SAME

HYDROGEN SENSOR BASED ON NICKEL/PALLADIUM-GRAPHENE NANOCOMPOSITE AND METHOD OF FABRICATING THE SAME

机译:基于镍/钯-石墨纳米复合物的氢传感器及其制造方法

摘要

The present invention relates to a nickel/palladium-graphene (Ni/Pd-Gr) nanocomposite-based hydrogen sensor and a method for manufacturing the same. A nanoparticle supporting graphene (Ni/Pd-Gr) of two metals of nickel/palladium (Ni/Pd) is synthesized by a simple chemical method and the post annealing process. As a feature of a hydrogen (H_2) sensor comprising a small amount of Ni added to specific resistance type Pd nanoparticles (Pd NPs), and Pd-Gr nanoparticles, Pd NPs is synthesized by changing the molar ratio of a Ni-Pd precursor with different amounts of Ni planted in a Pd grid. As a result of the present invention, the addition of Ni indicates not only to strengthen the ability to perform a hydrogen (H_2) sensor-based Pd-Gr composite, but also to offset hysteresis behavior. H_2 can be detected to 1-1000 ppm based on a complete and quick recovery response with a relevant Ni/Pd ratio. In the optimal Ni/Pd ratio of 7% (Ni/Pd-7%), the sensor indicates to strengthen distinct sensitivity and the reaction time, and there is no hysteresis behavior. As Ni is added to Pd NPs in a hydrogen (H_2) sensor which is based on a Pd-Gr nano composite, structural stability and reliability are improved.
机译:本发明涉及镍/钯-石墨烯(Ni / Pd-Gr)纳米复合材料基氢传感器及其制造方法。通过简单的化学方法和后退火工艺合成了镍/钯(Ni / Pd)两种金属的纳米粒子支撑石墨烯(Ni / Pd-Gr)。作为氢(H_2)传感器的特征,该传感器包括向特定电阻型Pd纳米颗粒(Pd NPs)和Pd-Gr纳米颗粒中添加的少量Ni,通过改变Ni-Pd前驱体的摩尔比来合成Pd NPs。在Pd栅格中种植不同数量的Ni。作为本发明的结果,Ni的添加不仅表明增强了执行基于氢(H_2)传感器的Pd-Gr复合材料的能力,而且还抵消了滞后行为。基于具有相关的Ni / Pd比的完整而快速的恢复响应,可以将H_2检测到1-1000 ppm。在7%的最佳Ni / Pd比(Ni / Pd-7%)中,传感器指示增强了明显的灵敏度和反应时间,并且没有磁滞现象。由于将Ni添加到基于Pd-Gr纳米复合材料的氢(H_2)传感器中的Pd NP中,因此提高了结构稳定性和可靠性。

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