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FILM FORMED FROM A BLEND OF BIODEGRADABLE ALIPHATIC-AROMATIC COPOLYESTERS

机译:由可生物降解的脂肪族-芳香族共聚聚酯混合而成的薄膜

摘要

different aliphatic-aromatic copolyester film is provided formed from biodegradable polymer blends of polyester It is. More particularly, the blend contains the first copolyester formed from terephthalic acid monomer. The use of terephthalic acid monomers are generally linear structures (for example, ~ 180 ) 1,4- linked to (p -) results in a polymer chain containing a terephthalate unit. Also contain an aromatic co-polyester-blend formed from a second aliphatic acid and / or isophthalic acid monomers. The use of such a monomer is 1,2 (ortho -) and / or 1,3- (meta-) to produce a polymer chain containing units connected. 1,2 (ortho -) and / or 1,3- (meta-) if inclusion of the polymer into the main chain of the copolyester of the second unit is connected or not, or each, bending position, into the linear polymer chain, (for example, ~ 120 bending position by 1, 3-bond) is introduced. 'Bending position' in the main chain, the second copolyester has crystallinity, and its physical properties thereof reduces the melt viscosity affects (e.g., rigidity, tensile strength, and the crystallization rate). Thus, the properties of the second copolyester are practically different from those of the first copolyester. In this regard, the 'bending position' the second copolyester is superior than can be achieved using only one of the two co-polyester alone, it is possible to provide the flexibility to form a film having a wide range of properties. ;
机译:提供了由聚酯的可生物降解的聚合物共混物形成的不同的脂族-芳族共聚酯薄膜。更特别地,该共混物包含由对苯二甲酸单体形成的第一共聚酯。对苯二甲酸单体的使用通常是线性结构(例如,〜180),与(p-)连接的1,4-产生包含对苯二甲酸酯单元的聚合物链。还包含由第二种脂肪酸和/或间苯二甲酸单体形成的芳族共聚酯共混物。这样的单体的使用是1,2(邻-)和/或1,3-(间-)以产生包含连接的单元的聚合物链。如果在第二单元共聚酯的主链中是否包含聚合物,或者每个弯曲位置是否连接到线性聚合物链中,则为1,2(邻位-)和/或1,3-(间位) ,(例如,通过1、3键绑定〜120个弯曲位置)。第二共聚酯在主链中的“弯曲位置”具有结晶性,其物理性质降低了熔体粘度的影响(例如,刚性,拉伸强度和结晶速率)。因此,第二共聚酯的性质实际上与第一共聚酯的性质不同。就这一点而言,第二共聚酯的“弯曲位置”优于仅单独使用两种共聚酯中的一种可以实现的弯曲,可以提供柔性以形成具有广泛性能的膜。 ;

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