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Reducing the content of sulfides in industrial liquids IN THE OIL RECOVERY

机译:减少石油开采中工业液体中的硫化物含量

摘要

1. A method for processing liquid technical in a production well comprising: a) providing an oil production well in the oil reservoir, having a casing and the production tubing; b) introducing an aqueous solution containing at least one inorganic oxidizer, a well casing, wherein said solution flows along the casing and comes into contact with the technical fluid in the wellbore below the production tubing; and c) to obtain technical service pipe by fluids, wherein the concentration of sulfide in the fluid technology reduced over the concentration of sulfide in the technical liquid obtained without the step (b) .2. A method according to Claim. 1 wherein the inorganic oxidizer is a standard half cell potential higher than the reaction -0.478 B3. The method of claim. 2, wherein the inorganic oxidizer selected from the group consisting of permanganates, persulfates, inorganic peracids, chromates, bromates, iodates, chlorates, perchlorates, chlorites, hypochlorites, peroxides and inorganic oksidov.4. The method of claim. 3, where the inorganic oxidant is selected from the group consisting of chlorine dioxide, hypochlorite, peroxide and persulfate vodoroda.5. A method according to Claim. 1 wherein the inorganic oxidizer vklyuchaetnitrat ions, nitrite ions or a mixture of nitrate and nitrite ions ionov.6. The method of claim. 5, where the total molar concentration of nitrate ions, nitrite ions or a mixture of the nitrate ion and nitrite ion is at least five times higher than the molar concentration of sulphide in the technical fluids in the production well, measured prior to administration of the aqueous solution in step (b) .7. The method of claim. 5, wherein at IU
机译:1。一种用于在生产井中处理液体技术的方法,包括:a)在所述储油器中提供采油井,其具有套管和所述生产管; b)引入包含至少一种无机氧化剂的水溶液,井套管,其中所述溶液沿套管流动并与生产管道下方的井眼中的工业流体接触; c)通过流体获得技术服务管道,其中流体技术中的硫化物的浓度比没有步骤(b).2获得的工业液体中的硫化物的浓度降低。根据权利要求1的方法。 1,其中无机氧化剂的标准半电池电位高于反应-0.478 B3。权利要求的方法。参照图2,其中无机氧化剂选自高锰酸盐,过硫酸盐,无机过酸,铬酸盐,溴酸盐,碘酸盐,氯酸盐,高氯酸盐,亚氯酸盐,次氯酸盐,过氧化物和无机oksidov.4。权利要求的方法。 3,其中无机氧化剂选自二氧化氯,次氯酸盐,过氧化物和过硫酸盐味五。根据权利要求1的方法。 1,其中无机氧化剂vklyuchaetnitrat离子,亚硝酸根离子或硝酸根和亚硝酸根离子的混合物ionov.6。权利要求的方法。参见图5,其中在施用前,在生产井中测量的硝酸根离子,亚硝酸根离子或硝酸根离子和亚硝酸根离子的混合物的总摩尔浓度比生产井中工业流体中硫化物的摩尔浓度高至少五倍。步骤(b)中的水溶液.7。权利要求的方法。 5,其中IU

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