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CATALYST USED FOR RESOURCE UTILIZATION OF A FIXED BED ANILINE DISTILLATION RESIDUE AND METHOD FOR PREPARING SAID CATALYST

机译:用于固定床苯胺蒸馏残渣资源化的催化剂和制备所述催化剂的方法

摘要

The present invention relates to a catalyst for fixed bed aniline rectification residue recycling and preparation method thereof. Based on the total weight of the catalyst, the catalyst comprises the following components in percentage by weight: 5-40% of an active component, 2-30% of a first cocatalyst component, 10-30% of a second cocatalyst component and the balance of carrier, wherein the active component is NiO; the first cocatalyst component is one or more of Fe, Mo, Cr or Co oxide; and the second cocatalyst component is one or more of La, Zr, Y or Ce oxide. The catalyst is prepared through co-precipitation. The catalyst shows high activity and stability in the waste liquid treatment process, and can still maintain high rectification residue cracking rate after reaction of 200 hours.
机译:本发明涉及固定床苯胺精馏残渣回收的催化剂及其制备方法。基于催化剂的总重量,催化剂包含以下按重量百分比计的组分:5-40%的活性组分,2-30%的第一助催化剂组分,10-30%的第二助催化剂组分和载体的余量,其中活性成分为NiO;第一助催化剂组分是Fe,Mo,Cr或Co氧化物中的一种或多种;第二助催化剂组分是La,Zr,Y或Ce氧化物中的一种或多种。通过共沉淀制备催化剂。该催化剂在废液处理过程中表现出高活性和稳定性,反应200小时后仍可保持较高的精馏残渣裂化率。

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