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Method of reducing methods extracting electrons from the hydrogen molecule using a hydride metal complex, and a substrate

机译:使用氢化物​​金属配合物从氢分子中提取电子的还原方法和基板

摘要

PROBLEM TO BE SOLVED: To provide a method for reducing a substrate with a binuclear complex using a low-cost and abundant metal by using hydrogen.;SOLUTION: A method for reducing a substrate includes: a step to generate a nickel-iron hydride complex and proton by making a nickel-iron nitrile complex act on a hydrogen molecule and heterolytically activating the hydrogen molecule, and a step to reduce the substrate by making the nickel-iron hydride complex react with the substrate.;COPYRIGHT: (C)2014,JPO&INPIT
机译:解决的问题:提供一种通过使用氢气以低成本和丰富的金属来还原具有双核络合物的基质的方法;解决方案:一种用于还原基质的方法包括:生成氢化镍铁络合物的步骤通过使镍-铁腈配合物作用于氢分子并杂化活化氢分子而形成质子;以及使镍-铁氢化物配合物与底物反应以还原底物的步骤。;版权:(C)2014,日本特许厅

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