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Vinyl-cis - polybutadiene rubber manufacturing methods and vinyl-cis - polybutadiene rubber

机译:乙烯基-顺式-聚丁二烯橡胶的制造方法和乙烯基-顺式-聚丁二烯橡胶

摘要

PROBLEM TO BE SOLVED: To provide a method for producing vinyl-cis-polybutadiene rubber excellent in extrusion workability, tensile stress and fatigue resistance.;SOLUTION: The method for producing vinyl-cis-polybutadiene rubber comprises: mixing (A) vinyl-cis-polybutadiene which is obtained through (1) a step of preparing a mixed solution in which 1,2-polybutadiene is mixed to a mixture mainly composed of 1,3-butadiene and a hydrocarbon-based organic solvent to perform cis-1,4-polymerization of 1,3-butadiene and (2) a step of performing 1,2-polymerization of 1,3-butadiene at lower than 60°C in the presence of a catalyst obtained from a soluble cobalt compound, an organic aluminum compound represented by general formula AlR3, and carbon disulfide in the resulting polymerization reaction mixture; and (B) cis-polybutadiene which is obtained through a step of performing cis-1,4-polymerization of 1,3-butadiene with addition of a cis-1,4-polymerization catalyst.;COPYRIGHT: (C)2013,JPO&INPIT
机译:解决的问题:提供一种生产挤出加工性,拉伸应力和耐疲劳性优异的乙烯基-顺式-聚丁二烯橡胶的方法。解决方案:解决方法:该乙烯基-顺式-聚丁二烯橡胶的制造方法包括:混合(A)乙烯基-顺式-通过(1)的步骤制备的-聚丁二烯,其中将1,2-聚丁二烯混合到主要由1,3-丁二烯和烃基有机溶剂组成的混合物中以进行顺式-1,4的混合溶液聚合1,3-丁二烯和(2)在由可溶性钴化合物,有机铝化合物得到的催化剂的存在下,在低于60℃下进行1,3-丁二烯的1,2-聚合的步骤。所得的聚合反应混合物中,以通式AlR 3 表示,以及二硫化碳。 (B)顺式聚丁二烯,该步骤是通过在1,3-丁二烯中进行顺式1,4-丁二烯的顺式1,4-聚合反应并添加顺式1,4-聚合催化剂而制得的。版权所有:(C)2013,JPO&INPIT

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