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Method for producing iron methacrylate and hydroxyalkyl methacrylate

机译:甲基丙烯酸铁和甲基丙烯酸羟烷基酯的生产方法

摘要

There is provided a method for producing iron methacrylate being inexpensive, and being high in activity and selectivity and good in solubility to a reaction liquid when being used in production of a hydroxyalkyl methacrylate as a catalyst. The method for producing iron methacrylate for production of a hydroxyalkyl methacrylate according to the present invention includes subjecting a mixture of a metallic iron having an oxygen atom content by XRF analysis of the surface thereof of 6% by mass or lower, and methacrylic acid to a heat treatment at 95°C or higher and lower than 110°C for 100 to 600 min. The method for producing a hydroxyalkyl methacrylate according to the present invention includes reacting an alkylene oxide with methacrylic acid to produce the hydroxyalkyl methacrylate, wherein iron methacrylate produced by the method according to the present invention is used as a catalyst.
机译:本发明提供一种廉价的甲基丙烯酸铁的制造方法,该方法用于制造甲基丙烯酸羟烷基酯作为催化剂时,具有高的反应活性和选择性,并且对反应液的溶解性良好。根据本发明的用于生产甲基丙烯酸羟烷基酯的甲基丙烯酸铁的制备方法包括通过XRF分析其表面质量为6质量%以下的具有氧原子含量的金属铁与甲基丙烯酸的混合物。在95°C或更高且低于110°C的温度下进行100至600分钟的热处理。根据本发明的制备甲基丙烯酸羟烷基酯的方法包括使环氧烷与甲基丙烯酸反应以制备甲基丙烯酸羟烷基酯,其中通过根据本发明的方法制备的甲基丙烯酸铁用作催化剂。

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