首页> 外国专利> HIGHLY ACTIVE SELF-RECOVERABLE COMPOSITE OXIDE CATALYST FOR REVERSE WATER GAS SHIFT REACTION

HIGHLY ACTIVE SELF-RECOVERABLE COMPOSITE OXIDE CATALYST FOR REVERSE WATER GAS SHIFT REACTION

机译:用于逆水煤气变换反应的高活性自恢复复合氧化物催化剂

摘要

A disclosure is related to a composite oxide catalyst for a reverse water gas shift (RWGS) reaction, which is a reaction for obtaining water and carbon monoxide by reacting hydrogen with carbon dioxide, and particularly, to a self-recoverable composite oxide catalyst for a reverse water gas shift reaction, which is composed of a compound of Ce1-xMxO2-0.5x (M is one element selected from the group consisting of Y, La, Nd, Sm, and Gd) and Fe2O3 as a composite oxide, thus has an excellent thermal stability at high temperature, and has high carbon dioxide conversion and high carbon monoxide selectivity even under a strong reducing atmosphere, which is a process condition of the reverse water gas shift reaction. Also, the composite oxide exhibits excellent catalytic activity even at the reaction condition of low temperature such as 400° C., and thus enables a large amount of carbon dioxide to be removed at low cost.
机译:本发明涉及一种用于反向水煤气变换(RWGS)反应的复合氧化物催化剂,该反应是通过使氢与二氧化碳反应来获得水和一氧化碳的反应,特别是涉及一种用于水的自回收复合氧化物催化剂。由Ce 1-x M x O 2-0.5x 的化合物组成的逆向水煤气变换反应(M为一个元素选自Y,La,Nd,Sm和Gd)和Fe 2 O 3 作为复合氧化物,因此在高温下具有出色的热稳定性,并且即使在强还原气氛下也具有高的二氧化碳转化率和高的一氧化碳选择性,这是逆水煤气变换反应的工艺条件。而且,即使在低温如400℃的反应条件下,复合氧化物也表现出优异的催化活性,因此能够以低成本除去大量的二氧化碳。

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