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Water vapor adsorbent for adsorption heat pump, method for producing water vapor adsorbent, and adsorption heat pump including water vapor adsorbent

机译:用于吸附热泵的水蒸气吸附剂,水蒸气吸附剂的制造方法以及包括该水蒸气吸附剂的吸附热泵

摘要

There is provided a water vapor adsorbent for adsorption heat pumps that has high adsorption and desorption performance and high water resistance, such as submersion resistance. The water vapor adsorbent contains a zeolite that contains at least a silicon atom, an aluminum atom, and a phosphorus atom in its framework structure and that has a framework density of 12.0 T/1,000 cubic angstroms or more and 16.0 T/1,000 cubic angstroms or less, wherein the water vapor adsorbent contains a group 11 metal of the periodic table, which constitutes 0.1% to 15% by weight of the zeolite. In the zeolite containing the group 11 metal, an ion of the group 11 metal substitutes for a Bronsted acid site, which promotes a hydrolysis reaction of the zeolite, and decreases the number of Bronsted acid sites of the zeolite, thereby improving the water resistance, such as submersion resistance, of the zeolite.
机译:提供了一种用于吸附热泵的水蒸气吸附剂,其具有高吸附和解吸性能以及高耐水性,例如耐淹没性。所述水蒸气吸附剂包含在其骨架结构中至少包含硅原子,铝原子和磷原子并且其骨架密度为12.0T / 1,000立方埃以上且16.0T / 1,000立方埃或以下的沸石。更少,其中水蒸气吸附剂包含周期表的第11族金属,其占沸石重量的0.1%至15%。在含有第11族金属的沸石中,第11族金属的离子代替布朗斯台德酸位点,这促进了沸石的水解反应,并减少了沸石的布朗斯台德酸位点的数量,从而提高了耐水性,例如沸石的抗淹没性。

著录项

  • 公开/公告号US9387457B2

    专利类型

  • 公开/公告日2016-07-12

    原文格式PDF

  • 申请/专利权人 MITSUBISHI PLASTICS INC.;

    申请/专利号US201214352180

  • 发明设计人 HAIJUN CHEN;TAKAHIKO TAKEWAKI;

    申请日2012-10-01

  • 分类号B01J20/18;B01J20/30;B01D53/28;C01B39/54;F25B17/08;

  • 国家 US

  • 入库时间 2022-08-21 14:33:24

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