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Telechelic macromer, method for producing telechelic macromer and composition containing telechelic macromer

机译:远螯大分子单体,制备远螯大分子单体的方法和包含远螯大分子单体的组合物

摘要

A telechelic macromer is disclosed having (meth)acrylic end-groups and a core. The macromer defined by Formula 1 comprises a core Y (Formulas 2 to 9) that is linked to (meth)acrylic groups by urethane, ester or anhydride bonds and has iodine value ranging from 5 to 75. The method involves a chemical reaction carried out in solvent, ranging 6-24 hours, wherein the precursor of a core (Formulas 2 and 3) reacts in two stages with compounds forming urethane bonds, or wherein the precursor of a core (Formulas 4 to 8) reacts in one stage with compounds forming ester bonds, or wherein the precursor of a core defined by Formula 9 reacts in one stage with compounds forming anhydride bonds. The urethane, ester and anhydride moieties comprise groups capable of free radical polymerization isolating the final product by evaporation. The composition disclosed provides the macromer, a photoinitiator and possibly a reactive diluent.
机译:公开了一种具有(甲基)丙烯酸端基和核的远螯大分子单体。由式1定义的大分子单体包含通过氨基甲酸酯,酯或酸酐键与(甲基)丙烯酸基团连接的核Y(式2至9),并且碘值在5至75的范围内。该方法包括进行的化学反应。在溶剂中的反应时间为6-24小时,其中核芯的前体(式2和3)与化合物形成氨基甲酸酯键反应两个阶段,或者核芯的前体(式4至8)与化合物形成氨基甲酸酯键反应形成酯键,或其中式9定义的核的前体与形成酸酐键的化合物在一个阶段反应。氨基甲酸酯,酯和酸酐部分包含能够进行自由基聚合以通过蒸发分离出最终产物的基团。公开的组合物提供大分子单体,光引发剂和可能的反应性稀释剂。

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