III. methods to improve herbicide efficiency under severe water conditions and appropriate synthesis conditions

摘要

Requirement 1: a method for improving the efficacy of herbicide (b) under severe water conditions, characterized in that it comprises (a) stages of providing at least one herbicide (b) and at least one carbamate (a),Selected from the group of diethyl methacrylic acid (MGDA; A1),Ethyl glutamate (glda; A2),Pyridine formate (IDS; A3),N - (2-hydroxy) pyridine (Heida; A4),Ethylenediamine-N, N-SODIUM dichloride (EDDS; A5) and its salts; (b) the components (a) and (b) of the dilution water, in which the concentration of dissolved calcium, magnesium, iron salt and aluminum in the water exceeds 120 ppm; and (c) the diluted mixture is applied in the area concerned. 115. Claim 5: method of processing one to three claims, characterized by the concentration of dissolved calcium, magnesium, iron and aluminum salts in water exceeding 180 ppm. Claim 7: a method of meeting any of the above requirements,It is characterized by the selection of herbicides (b) from (B1) a (B5) (B1): "(B1) the selection of aromatic acid herbicides from dibenzo diazo, naparam, clovenin, diganba, Di, 3, 6-trichlorobenzoic acid (2, 3, 6-tb),Tricamba, bispyribac, pyrminobac, pyrithiobac, chlorothal, aminopyralid, halauxifen, picloram, quinorac, quinmerac or aminocyclepyrochlor; (B2) phenylacetic acid herbicide selected from 4-chlorophenol-tetraethyl acid (4-CPA);2,4-dichlorophenylacetic acid (2,4-D),Acetic acid (3,4-dichlorophenyl) acetic acid (3,4-da),MCPA (4 - (4-chloro-o-thyroid) butadiene acid)MCPA tioetilo, acid (2,4,5-trichlorophenyl) acetic anhydride (2,4,5-T);4-cpb, 4 - (2,4-dichlorophenyl) butyl (2,4-dichlorophenyl),4 - (3,4-dichlorophenyl) butyl (3,4-dichlorophenyl),4 - (4-chloro-o-thyroid) butadiene (mCPP),4 - (2,4,5-trichlorophenyl) butyl (2,4,5-tributyl) acid;2 - (4-chlorophenyl) propane (4-cpp),Dichloropropyl ester, dichloropropane-p, 4 - (3,4-dichlorophenyl) butadiene (3,4-dp),Phenol, mecoprop, Mecoprop-P; chlorozifop, Clodinafop, clophop, cyhalofp, Diclofop, fenxaprop, fenxaprop-p, fentiarp, fluazifop, fluazifop-p, haloxyfop, haloxyfop, haloxyfop-P, isoxapyrifop, Metamifop, propaquiza FOP, quiclafop, quislofp, quiclafop, quiclafop, trifop; (B3) organophosphorus herbicides, including a group of anthrax acids selected from bialafos, glufosinate, glufosinate-p and glyphost; (B4) other herbicides, including a carboxypyr acid selected from fluthrin, triclopyr, loransulam, bensulfuron, Chlorimuron, Foramsulfuron, halosulfuron and primeuron, Sulfamide, imazamethabanz, Imazamox, imazpic, Imazapyr, imazakin, imazathapyr,Fluclobazone, proposxycarbazone, thienarabzone, aculffonfen, bifenx, carfentrazone, flufenpyr, fluclorac, floglycogen, flutiacet, iactofen, pyrfalufen, chloroflurrenol, dalapon, endotal, flamrop-m, flupronete, flurrenol, oleico acid, pelagonic acid; (B5) other weak acid herbicides - 3-1,4-1,4-nitrogen-3-3-3-3-3-1,3-3-3-3-3-3-3-3-3-3-3-3-3-3-3-3-3-3-3 CAS 1258836-72-4,Clethodim, sethoxydim, cycloxydim, profoxydim, Tepraloxydim, Tralkoxydim, amidosulfron, azimsulfuron, bensulfuron, bensulfuron methyl, bensulfuron, Chlorimuron ethyl, Chlorosulfuron, cinosulfuron, cyclosulfuron, ethamethuron, ethamethuron methyl, ethoxysulfuron, flazuron, fluceurn, flucetopyron, methylsulfur, Fransulfuron, halogenated sulfur, halogenated sulfur methyl, imazofluoron, Iodosulfuron, iodosulfron methyl, methylmethylmethyl, methylmethylmethylmethyl, methylpolycyanofluor, methylsulfonyl fluoride, acryloyl fluoride, prosulon, pyrazozulon, pyrozulon Furun, diene sulfide, sulfonyl fluoride, methyl Sulphur3. Sulfur methyl, sulfur, thifenulfuron, thifenulfuron methyl, thifenulfuron methyl, trisulfuron, tribenoron, tribenoron methyl, trifloxysulfron, trifluuron, triflu sulphonyl methyl, triflusulfuron and bentazone and their useful derivatives in agriculture. Claim 8: a method meeting any of the above requirements, characterized in that the herbicide (b) is selected from the following groups: dicamba, 2, 4-D, quiclafop, quiclafop-p, glufosinate, glyphosate, sethoxydim,Clethodim and its useful derivatives in agriculture. 1. Claim 10: aminobenzene (a) selected from the group of methyl diethylformate (MGDA; a 1) is used,Ethyl glutamate (glda; A2),Pyridinecarboxylic acid (1240ds; A3) n - (2-hydroxy) pyridine (Heida; A4),Ethylenediamine-N, n-dichlorocyanate (EDDS; A5) and its salts are used to improve the effectiveness of anionic herbicide (b) in hard water. In hard water, the concentration of dissolved calcium, magnesium salt, iron and aluminum exceeds 120 ppm. Claim 19: a component having the properties of (a) one or more carbamates (a);Selected from the group of diethyl methacrylic acid (MGDA; A1),Ethyl glutamate (glda; A2),Pyridine formate (IDS; A3),N - (2-hydroxy) pyridine (Heida; A4),1. Ethylenediamine-N, n-dichlorocyanate (EDDS; A5) and its salts, wherein carbamate (a) does not conflict with transition metal; and (b) at least one herbicide;In addition to a specific group of herbicide compounds consisting of organophosphates, organophosphates, organophosphates and their respective salts, and components consisting of amidoacetamide-n, n-dinitrocarbonates (EDDS; A5) and / or their salts, As a herbicide (b), it is exactly a herbicide compound, which is selected from the soluble auxina herbicides in water, including sulfanilamide, clopyrid, 2,4-D, dicamba, dichloroprop, florixypyr, MCPA, MEC, picloram, quinorac, quinmerac, triclopyr and their useful derivatives in agriculture;In addition to the complexes of amidoacetamide-n, n-dinitrocarboxylate (EDDS; A5) and / or its salts and herbicides (b), they also include 2,4-D, dicamba and mecoprop and / or their useful derivatives in agriculture. Requirement 27: a method of controlling poor vegetation, characterized by permitting the application of herbicides in effective quantities in plants, seeds and / or habitats in accordance with any one of 19 to 22 requirements.