首页> 外国专利> Derivatives of bis(2,2'-bithienyl)methane and methods for producing them, layer of the identifying polymer produced by molecular typing method and the method for obtaining it, as well as application for selective determination and releasing nicotine

Derivatives of bis(2,2'-bithienyl)methane and methods for producing them, layer of the identifying polymer produced by molecular typing method and the method for obtaining it, as well as application for selective determination and releasing nicotine

机译:双(2,2'-二噻吩基)甲烷的衍生物及其制备方法,分子分型法制备的识别聚合物层及其制备方法,以及在选择性测定和释放烟碱中的应用

摘要

the subject of the invention are derivatives of bis (2,2 '- bitienylo) methane, containing substituent zinc phthalocyanine or substituted 2 - hydroksyetylenowy, preferably bis (2,2' - bitienylo) - (4 - (2 - hydroxy - ethoxy) phenyl) methane, etoh - s2, and 2,9,16,23 - tetraphenyl-1,1 '(4 - methyl - bis (2,2' - bitienylo)) ftalocyjaninato zinc (ii) , znpc - s8, and methods of their manufacture.the invention also includes a polymer layer pattern formed by molecular wdrukowania, characterised by that it is a polymer containing a bis (2,2 '- bitienylo) methane and method obtaining, characterised by that function as a monomer to e lektropolimeryzacji apply derivative of bis (2,2 '- bitienylo) - methane.moreover, in the preceding stage wdrukowanie molecular in the solution, a pre - polimeryzacyjny complex by creating a binding between a substituent zinc phthalocyanine monomer coordination znpc - s8 and the atom of hydrogen and pirydynowego nicotine binding between group - oh podstawnika 2 - hydroksyetylenowego monomer etoh - s2 and the nitrogen of the pyrrolidone ring of nicotine.the invention also includes the use of the polymer pattern as part of the pattern sensor to detect chemical and / or determination of nicotine, as well as release nicotine into the solution.
机译:本发明的主题是双(2,2'-双亚苯基邻氨基)甲烷的衍生物,其含有取代基酞菁锌或取代的2-羟基戊烯基,优选双(2,2'-双亚苯基邻氨基)-(4-(2--羟基-乙氧基)苯基)甲烷,乙二胺-s2和2,9,16,23-四苯基-1,1'(4-甲基-双(2,2'-苯二胺基))邻苯二甲醛锌(ii),znpc-s8和方法本发明还包括由分子屈曲花尼亚形成的聚合物层图案,其特征在于它是包含双(2,2'-二苯胺基)甲烷的聚合物及其获得方法,其特征在于其作为lektropolimeryzacji的单体起作用应用双(2,2'-bitienylo)-甲烷的衍生物。此外,在溶液的前阶段wdrukowanie分子中,通过在取代基酞菁锌单体配位体znpc-s8与s原子上形成结合,形成pre- polimeryzacyjny络合物氢和pirydynowego尼古丁之间的绑定组-哦podstawnika 2-羟基乙炔基乙炔单体etoh-s2和尼古丁吡咯烷酮环的氮。本发明还包括使用聚合物图案作为图案传感器的一部分来检测尼古丁的化学和/或测定,以及将尼古丁释放到溶液中。

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