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POLYPROPYLENE IN-REACTOR ALLOY COMPOSITION AND PREPARATION METHOD THEREFOR

机译:聚丙烯反应器合金的组成及其制备方法

摘要

Provided are a polypropylene in-reactor alloy composition and a preparation method therefor. The preparation method for the polypropylene in-reactor alloy composition comprises propylene undergoing a polymerisation reaction in the presence of an olefin polymerisation catalyst component and a cocatalyst, then ethylene and an α-olefin being passed through the polymerisation reaction system and the polymerisation reaction being continued, the olefin polymerisation catalyst component containing halloysite, a transition metal component and a non-transition metal component. When the transition metal component is a titanium tetrahalide and/or a titanium alkoxide, the non-transition metal component is a magnesium-containing compound. When the transition metal component is a metallocene compound and/or a non-metallocene compound, the non-transition metal component is an aluminium-containing compound. When the transition metal component is mixture of a titanium tetrahalide and/or a titanium alkoxide and a metallocene compound and/or a non-metallocene compound, the non-transition metal component is a mixture of a magnesium-containing compound and an aluminium-containing compound. The polypropylene in-reactor alloy composition has a relatively high melt strength and relatively high mechanical properties.
机译:提供了一种聚丙烯反应器内合金组合物及其制备方法。聚丙烯反应器内合金组合物的制备方法包括:使丙烯在烯烃聚合催化剂组分和助催化剂的存在下进行聚合反应,然后使乙烯和α-烯烃通过聚合反应体系并使聚合反应继续进行。 ,该烯烃聚合催化剂组分包含埃洛石,过渡金属组分和非过渡金属组分。当过渡金属成分为四卤化钛和/或钛醇盐时,非过渡金属成分为含镁化合物。当过渡金属组分是茂金属化合物和/或非茂金属化合物时,非过渡金属组分是含铝化合物。当过渡金属组分是四卤化钛和/或钛醇盐与茂金属化合物和/或非茂金属化合物的混合物时,非过渡金属组分是含镁化合物和含铝化合物的混合物。复合。聚丙烯反应器内合金组合物具有较高的熔体强度和较高的机械性能。

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