首页> 外国专利> PHENYL-MODIFIED HYBRID PREPOLYMER, PHENYL-MODIFIED POLYDIMETHYLSILOXANE-BASED HYBRID PREPOLYMER, AND PHENYL-MODIFIED POLYDIMETHYLSILOXANE-BASED HYBRID POLYMER, AND PRODUCTION PROCESSES THEREFOR

PHENYL-MODIFIED HYBRID PREPOLYMER, PHENYL-MODIFIED POLYDIMETHYLSILOXANE-BASED HYBRID PREPOLYMER, AND PHENYL-MODIFIED POLYDIMETHYLSILOXANE-BASED HYBRID POLYMER, AND PRODUCTION PROCESSES THEREFOR

机译:苯甲酰改性的混合预聚物,苯甲酰改性的聚二甲基硅氧烷的杂化预聚物和苯甲酰改性的聚二甲基硅氧烷的杂化聚合物,及其制备方法

摘要

Provided are a phenyl-modified hybrid prepolymer, a phenyl-modified polydimethylsiloxane-based hybrid prepolymer, and a phenyl-modified polydimethylsiloxane-based hybrid polymer, in which the material hardness or the surface tackiness can be controlled in accordance with uses or purposes. The phenyl-modified hybrid prepolymer (B) is produced by subjecting a polydimethylsiloxane having a trialkoxysilyl group at each of both terminals, a phenyltrialkoxysilane, and a diphenyldialkoxysilane to a hydrolysis/condensation reaction. The phenyl-modified polydimethylsiloxane-based hybrid prepolymer (C) comprises the prepolymer (B) and is preferably produced by mixing the prepolymer (B) with a phenyl-modified hybrid prepolymer (A) produced by subjecting a polydimethylsiloxane having a silanol group at each of both terminals and a phenyltrialkoxysilane to a condensation reaction. The phenyl-modified polydimethylsiloxane-based hybrid polymer is obtained by heating and solidifying the prepolymer (C).
机译:提供了苯基改性的杂化预聚物,苯基改性的聚二甲基硅氧烷基杂化预聚物和苯基改性的聚二甲基硅氧烷基杂化聚合物,其中可以根据用途或目的来控制材料硬度或表面粘性。通过使在两个末端均具有三烷氧基甲硅烷基的聚二甲基硅氧烷,苯基三烷氧基硅烷和二苯基二烷氧基硅烷进行水解/缩合反应,来制备苯基改性的杂化预聚物(B)。所述苯基改性的聚二甲基硅氧烷基杂化预聚物(C)包含所述预聚物(B),并且优选通过将所述预聚物(B)与通过使各自具有硅烷醇基的聚二甲基硅氧烷均经过制备的苯基改性的杂化预聚物(A)混合而制备。两个末端与苯基三烷氧基硅烷的缩合反应。通过加热和固化预聚物(C)获得苯基改性的基于聚二甲基硅氧烷的杂化聚合物。

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