首页> 外国专利> ELECTROCHEMICAL GAS SENSOR WITH IONIC LIQUID AS AN ELECTROLYTE FOR DETECTION OF AMMONIA AND AMINES

ELECTROCHEMICAL GAS SENSOR WITH IONIC LIQUID AS AN ELECTROLYTE FOR DETECTION OF AMMONIA AND AMINES

机译:离子液体作为检测氨和胺的电解质的电化学气体传感器

摘要

1. An electrochemical gas sensor, comprising: an electrolyte containing an ionic liquid, wherein said ionic liquid contains at least one proton ammonium cation with at least one dissociable hydrogen atom, said at least one proton ammonium cation reacting with the target gas by deprotonation. 2. The gas sensor according to claim 1, characterized in that the target gas contains at least one component selected from the group consisting of: ammonia and amines. A gas sensor according to claim 1, characterized in that said gas sensor is designed to detect at least one predetermined gas selected from the group consisting of: ammonia and amines. The gas sensor according to claim 1, characterized in that said at least one proton ammonium cation has a pKa value less than about 9.25.5. The gas sensor according to claim 1, characterized in that said at least one proton ammonium cation is selected from the group consisting of: a monosubstituted ammonium cation; disubstituted ammonium cation; and a trisubstituted ammonium cation. 6. A gas sensor according to claim 1, characterized in that said at least one proton ammonium cation contains at least one substituent having at least one electron-withdrawing group. The gas sensor according to claim 6, wherein said at least one substituent having at least one electron withdrawing group contains at least one alkyl group selected from the group consisting of: branched C1-C20 alkyl groups; and unbranched C1-C20 alkyl groups; at least one aryl and / or
机译:1.一种电化学气体传感器,包括:包含离子液体的电解质,其中所述离子液体包含具有至少一个可解离氢原子的至少一个质子铵阳离子,所述至少一个质子铵阳离子通过去质子化与目标气体反应。 2.根据权利要求1所述的气体传感器,其特征在于,所述目标气体包含选自由氨和胺组成的组中的至少一种成分。 2.根据权利要求1所述的气体传感器,其特征在于,所述气体传感器被设计为检测选自氨和胺中的至少一种预定气体。 2.根据权利要求1所述的气体传感器,其特征在于,所述至少一种质子铵阳离子的pKa值小于约9.25.5。 2.根据权利要求1所述的气体传感器,其特征在于,所述至少一种质子铵阳离子选自:单取代铵阳离子;和双取代铵阳离子;和三取代铵阳离子。 6.如权利要求1所述的气体传感器,其特征在于,所述至少一种质子铵阳离子包含至少一种具有至少一个吸电子基团的取代基。 7.根据权利要求6所述的气体传感器,其特征在于,所述至少一个具有至少一个吸电子基团的取代基包含选自由支链的C 1 -C 20烷基组成的组中的至少一个烷基。和非支链的C1-C20烷基;至少一个芳基和/或

著录项

  • 公开/公告号RU2014120795A

    专利类型

  • 公开/公告日2015-12-10

    原文格式PDF

  • 申请/专利权人 МСА ЮРОП ГМБХ (CH);

    申请/专利号RU20140120795

  • 发明设计人 ВАРРАТЦ РАЛЬФ (DE);

    申请日2012-10-25

  • 分类号G01N27/404;

  • 国家 RU

  • 入库时间 2022-08-21 14:11:31

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