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Oral and hygiene products with photocatalytic activity, which include particles of inorganic substances, surface-functional nanoparticles

机译:具有光催化活性的口腔和卫生产品,包括无机物质颗粒,表面功能纳米颗粒

摘要

1. A product for oral care and oral hygiene with photocatalytic activity, which includes calcium phosphate compound particles surface-functionalized with TiO nanoparticles in crystalline form, while these TiO nanoparticles have the following characteristics: a) predominantly layered morphology; b) coefficient compressions from 5 to 30; c) a surface structure having the front side (001), which is the surface of the crystal lattice farthest from the center; and d) TiO is represented in them in the form of anatase, sometimes mixed with rutile and / or brookite. 2. A product according to claim 1, wherein the particles of the phosphate compound are micrometric in size, preferably in the length range from 0.2 to 10 microns. A product according to claim 1, wherein the TiO nanoparticles have a length of less than 0.1 μm, preferably in the range from 0.01 to 0.1 μm. The product according to claim 1, in which the TiO nanoparticles have a thickness in the range from 2 to 5 nm. The product according to claim 1, wherein the calcium phosphate compound is selected from the group consisting of: octacalcium phosphate, tricalcium phosphate, apatite, hydroxyapatite and hydroxyapatite carbonate. The product according to claim 1, wherein the calcium phosphate compound further comprises zinc ions and / or carbonate ions. The product of claim 1, wherein the particles of the calcium phosphate compound have a surface with free positive and / or negative charges. The product according to claim 1, wherein the calcium phosphate compound particles surface-functionalized with TiO nanoparticles have a degree of crystallinity (CD) ranging from 50 to 80%, preferably from 58 to 75%. The product of claim 1, in the form of a suspension oil, gel or solid. The product according to claim 9, in the form of a suspension, which includes from 1 to 40% of the masses indicated
机译:1.具有光催化活性的用于口腔护理和口腔卫生的产品,其包括用结晶形式的TiO纳米颗粒表面功能化的磷酸钙化合物颗粒,而这些TiO纳米颗粒具有以下特征:a)主要为层状形态; b)从5压缩到30; c)具有正面(001)的表面结构,该正面是距中心最远的晶格表面; d)TiO以锐钛矿形式存在,有时与金红石和/或板钛矿混合。 2.根据权利要求1的产品,其中所述磷酸盐化合物的颗粒的尺寸为微米级,优选长度为0.2至10微米。 3.根据权利要求1的产品,其中所述TiO纳米颗粒的长度小于0.1μm,优选在0.01至0.1μm的范围内。 2.根据权利要求1的产品,其中所述TiO纳米颗粒的厚度为2至5nm。 2.根据权利要求1的产品,其中磷酸钙化合物选自:磷酸八钙,磷酸三钙,磷灰石,羟基磷灰石和碳酸羟基磷灰石。 2.根据权利要求1所述的产品,其中,所述磷酸钙化合物还包含锌离子和/或碳酸根离子。 2.权利要求1的产品,其中磷酸钙化合物的颗粒的表面具有自由的正电荷和/或负电荷。 2.根据权利要求1的产品,其中用TiO纳米颗粒表面官能化的磷酸钙化合物颗粒的结晶度(CD)为50至80%,优选为58至75%。权利要求1的产品,其为悬浮油,凝胶或固体形式。 10.根据权利要求9的产品,其为悬浮液形式,其包含1至40%的所示质量。

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