A method for the production of (10 / 11 / 12) - pentadecene - 15 - olid starting from 11 - and / or 12 - pentadecene - 15 - olid

摘要

A process for the preparation of a (e, z) - 10,11,12 - pentadecene - 15 - olid - isomer mixture, with the following step:– Partial isomerization of (e, z) - 11 - and / or (e, z) - 12 - pentadecene - 15 - olid, so that the (e, z) - (10 / 11 / 12) - pentadecene - 15 - olid - isomer mixture is produced, wherein the (e, z) - 11 - and / or (e, z) - 12 - pentadecene - 15 - olid so with(i) a catalyst,that it is partially with the formation of the (e, z) - (10 / 11 / 12) - pentadecene - 15 - olid - isomer mixture of isomerized,wherein the catalyst is selected from the group consisting ofRhodium (iii) - bromide hydrate, rhodium (iii) - chloride, rhodium (iii) - chloride hydrate, rhodium (iii) - iodide hydrate, rhodium (iii) - nitrate, rhodium (iii) - phosphate, rhodium (iii) - sulfate, rhodium (ii) - acetate dimer, rhodium (iii) acetylacetonate, rhodium (i) - to - (1,5 - cyclooctadiene) - tetrafluoroborate hydrate, rhodium (i) - to - (1,5 - cyclooctadiene) - acetylacetonate, rhodium (i) - to - (1,5 - cyclooctadiene) - chloride dimer, rhodium (i) - to - (1,5 - cyclooctadiene) - trifluoromethanesulfonate dimer, rhodium (i) - [1,4 - to - (diphenylphosphino) - butane] - (1c, 5c - cyclooctadiene) - tetrafluoroborate, rhodium (i) - [1,4 - to - (diphenylphosphino) - butane] - ((2,5 - norbornane diene) - tetrafluoroborate, rhodium (i) - (2,5 - norbornane diene) - perchlorate, rhodium (i) - to - (triphenylphosphine) - carbonyl - chloride, rhodium (ii) - trifluoroacetate dimer, rhodium (i) - tris - (triphenylphosphine) - bromide, rhodium (i) - tris - (triphenylphosphine) - chloride, rhodium (i) - dicarbonyl - acetylacetonate, rhodium (i) - dicarbonyl - chloride dimer,Ruthenium (iii) - bromide hydrate, ruthenium (iii) - chloride, ruthenium (iii) - chloride hydrate, ruthenium (iii) - iodide, ruthenium carbonyl, ruthenium (i) - acetate polymer, ruthenium (iii) - acetylacetonate, ruthenium (ii) - (1,5 - cyclooctadiene) - chloride polymer, ruthenium (ii) - tris - (triphenylphosphine) - chloride, ruthenium (ii) - tricarbonyl - chloride dimer, ruthenium (ii) - carbonyldihydrido - tris - (triphenylphosphine), ruthenium (iii) - 2,4 - pentanedionat,Palladium (ii) - acetate, palladium (ii) - acetylacetonate, palladium (ii) - to - (acetonitrile) - chloride, palladium (ii) - to - (benzonitrile) - chloride, palladium (ii) - [1,2 - to - (diphenylphosphino) - ethane] - chloride, palladium (ii) - to (tricyclohexylphosphine) - chloride, palladium (ii) - to - (triphenylphosphine) - chloride, palladium (ii) - to - (triphenylphosphine) - bromide, palladium (ii) - bromide, palladium (ii) - chloride, palladium (ii) - diammine - chloride, palladium (ii) - iodide, palladium (ii) - nitrate, palladium (ii) - 2,5 - norbornadiene - chloride, palladium (ii) - sulfate, palladium (ii) - tetra mmin - chloride, palladium (ii) - [1,1 '- ferrocenylbis (diphenylphosphane)] - dichloride dichloromethane, palladium on activated carbon, palladium on aluminium oxide,Iridium acetate, iridium (iii) - acetylacetonate, iridium (i) - to - (triphenylphosphine) - carbonyl - chloride, iridium (iii) - bromide hydrate, iridium, carbonyl, iridium (iii) - chloride, iridium (iii) - chloride hydrate, iridium (i) - (1,5 - cyclooctadiene) - acetylacetonate.