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An oxidation catalyst of non-stoichiometric perovskite oxide for the oxidation of no to no2 in an exhaust gas aftertreatment system and method

机译:非化学计量钙钛矿氧化物的氧化催化剂,用于在废气后处理系统和方法中将no氧化为no2

摘要

A method for the oxidation of no to no2 in an exhaust gas aftertreatment system for a motor which is operated with hydrocarbon, comprising:(a) supplying a mixture of air and fuel to a motor which is operated with hydrocarbon, wherein the mixture of air and fuel through an air - fuel - mass ratio is defined, which is more than stoichiometric,(b) combustion of the mixture of air and fuel in the motor which is operated with hydrocarbon with the generation of exhaust gas flow (12), one of the noX-Content, wherein the noX-Content of no and no2 in a molar ratio of no to no2 , and(c) exposing of the exhaust gas flow (12) of an oxidation catalyst with an activity for the oxidation of no to no2, which is sufficient to ensure that the molar ratio of no to no2 of the noX-Content of the exhaust gas flow (12) so as to reduce the oxidation catalytic converter from particles of a perovskite oxide having the formula la.sub.2XMnoY in the x in the range from 0,85 – 0,95, and in a load of 5 – 200 g / l of the volume flow rate by means of the particles consisting of laXMnoY-Perovskite oxide are present,characterized in thatit is a question of non-stoichiometric perovskite oxide is,Y in the range from 3,19 – 3,30, andthe particles of non-stoichiometric laXMnoY-Perovskite oxide have a diameter in the range from 10 nm – 100 μm is.
机译:在用碳氢化合物运行的电动机的废气后处理系统中将no氧化成no 2 的方法,该方法包括:(a)向运行的电动机供应空气和燃料的混合物碳氢化合物,其中通过空气-燃料-质量比定义的空气和燃料混合物大于化学计量比, No X 含量之一的废气流(12),其中no和no 2 的no X -含量no与no 2 的比率,以及(c)暴露具有no to no 2 的氧化活性的氧化催化剂的排气流(12),这足以确保废气流中no X 含量的no与no 2 的摩尔比,从而减少氧化催化转化器由具有该式的钙钛矿氧化物的颗粒x中的la.sub.2 X Mno Y 范围为0.85-0.95,负载为5-200 g / l存在由la X Mno Y -钙钛矿氧化物组成的颗粒的体积流量,其特征在于非化学计量的钙钛矿氧化物为非化学计量的la X Mno Y -钙钛矿氧化物的粒径范围为10 nm – 100微米

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