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SURFACE-MODIFIED SEPARATION MEMBRANE AND METHOD FOR MODIFYING SURFACE OF SEPARATION MEMBRANE

机译:表面改性的分离膜及分离膜的表面改性方法

摘要

A surface-modified separation membrane of the present invention comprises a separation membrane, and a coating layer formed on the surface of the separation membrane for improving the contamination resistance and chemical resistance of the separation membrane, wherein the coating layer is implemented with a nanoscale thickness of the coating layer in order to inhibit a decrease in permeation flux of the separation membrane before and after coating the coating layer, and comprises: dopamine for providing, to the coating layer, an adsorption force to be bound stably with the separation membrane; and a hydrophilic material which is bound to the dopamine through secondary bonding or cross-linking containing a hydrogen bond in order to inhibit the deterioration of the durability of the coating layer, and provides hydrophilicity to the surface of the separation membrane in order to protect the separation membrane from hydrophobic contaminants. A method for modifying the surface of a separation membrane of the present invention comprises the steps of: injecting a separation membrane to be surface-modified into a reactor; adding a mixture solution, which is formed by adding a hydrophilic material to a Tris-buffer solution having an adjusted pH range at which dopamine reacts and stirring the same, to the reactor; adding dopamine and an initiator, which induces the cross-linking of the hydrophilic material and dopamine, to the reactor at a predetermined temperature range; and forming a coating layer comprising dopamine and the hydrophilic material on the separation membrane through thermal cross-linking at the predetermined temperature range while injecting oxygen into the reactor.
机译:本发明的表面改性分离膜包括分离膜和形成在分离膜表面上的涂层,该涂层用于提高分离膜的耐污染性和耐化学性,其中该涂层以纳米级的厚度实现。为了抑制涂布膜在涂布之前和之后渗透膜的渗透通量降低而使用的涂布膜,其包括:多巴胺,用于向涂布层提供与分离膜稳定地结合的吸附力;亲水性材料,其通过包含氢键的二次键合或交联而与多巴胺结合,从而抑制涂层的耐久性下降,并且为分离膜的表面提供亲水性以保护膜层表面。从疏水性污染物分离膜。本发明的分离膜的表面改性方法包括以下步骤:将要进行表面改性的分离膜注入到反应器中;以及将待表面改性的分离膜注入反应器中。向反应器中添加混合溶液,该混合溶液是通过将亲水性材料添加到具有调节的pH范围的Tris-缓冲溶液中形成的,该Tris-缓冲溶液在多巴胺反应的pH范围内搅拌。在预定温度范围内,将多巴胺和引发剂引入多巴胺和引发剂中,所述引发剂引起亲水性材料和多巴胺的交联。通过在预定温度范围内进行热交联,同时将氧气注入反应器中,在分离膜上形成包含多巴胺和亲水性材料的涂层。

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