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SPECTROSCOPIC QUANTIFICATION METHOD, AND SPECTROSCOPIC QUANTIFICATION DEVICE AND PROGRAM
SPECTROSCOPIC QUANTIFICATION METHOD, AND SPECTROSCOPIC QUANTIFICATION DEVICE AND PROGRAM
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机译:光谱定量方法,光谱定量装置和程序
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摘要
A composition ratio of a component targeted for quantification in a liquid, solid, or gaseous mixture is determined without taking the effort of performing measurement while stepwise changing an addition concentration as in an existing standard addition method. A quantitative spectrometry apparatus 100 includes a measurement unit 110 that spectroscopically analyzes an analysis-target sample 10 containing a component targeted for quantification in an unknown composition ratio and a reference sample containing the component targeted for quantification in a known composition ratio to obtain an original spectrum and a reference spectrum, a first generation unit 130 that generates, from these spectra, hypothetical addition spectra including a plurality of hypothetical addition rates as coefficients, a second generation unit that generates a plurality of analysis-target spectra from the respective hypothetical addition spectra, an extraction unit 170 that extracts a signal intensity profile of the component targeted for quantification corresponding to the hypothetical addition rates by performing a process including multivariate analysis, and a determination unit 190 that determines the unknown composition ratio of the component targeted for quantification contained in the analysis-target sample 10 from the dependence of the signal intensity profile on the hypothetical addition rates.
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