首页> 外国专利> MANUFACTURING METHOD FOR HIGHLY DISPERSABLE PARTICULATE INORGANIC FILLER AND DENTAL CURABLE COMPOSITION COMPRISING PARTICULATE INORGANIC FILLER

MANUFACTURING METHOD FOR HIGHLY DISPERSABLE PARTICULATE INORGANIC FILLER AND DENTAL CURABLE COMPOSITION COMPRISING PARTICULATE INORGANIC FILLER

机译:高度分散的颗粒状无机填料的制造方法和包含颗粒状无机填料的牙科可固化组合物

摘要

PROBLEM TO BE SOLVED: To solve the following problem: inorganic fillers are generally added to composite resins for increase in the mechanical strength and in the operability thereof; specifically, inorganic fillers with a median diameter of less than 0.5 μm are added for increased operability, and inorganic filler with a median diameter in a range from 0.5 μm to 100 μm are added for increased mechanical strength which is brought by further increase in the filling rate; with respect to the increase in the filling rate, inorganic fillers are surface-treated by a silane coupling agent to improve wettability, which results in the increase in the filling rate, further leading to increase in the elasticity modulus of the hardening body to thereby increase the mechanical strength; however, the conventional silane coupling treatment is limited in the increase in the wettability, so that sufficient filling rate cannot be achieved, and thus the mechanical strength cannot be increased sufficiently.SOLUTION: A particulate inorganic filler is manufactured by a method comprising the steps of: (1) surface-treating inorganic particulates with a silane coupling agent; and (2) suspending the inorganic particulates treated by the silane coupling agent in a water-containing organic solvent and adding an electrolyte to the suspended inorganic particulates. It is found that the thus manufactured particulate inorganic filler is highly dispersable in a dental curable composition composed of a radical polymerizable monomer, and that the particulate inorganic filler can be filled in the dental curable composition at a higher filling rate.SELECTED DRAWING: None
机译:解决的问题:为了解决以下问题:通常将无机填料添加到复合树脂中以提高机械强度和其可操作性。具体地,添加中值直径小于0.5μm的无机填料以提高可操作性,并且添加中值直径在0.5μm至100μm范围内的无机填料以提高机械强度,这由填充的进一步增加而带来。率;关于填充率的提高,无机填料通过硅烷偶联剂进行表面处理以提高润湿性,这导致填充率的提高,进一步导致硬化体的弹性模量增加,从而增加了填充率。机械强度然而,常规的硅烷偶联处理在润湿性的增加上受到限制,从而不能获得足够的填充率,因此不能充分提高机械强度。解决方案:颗粒状无机填料是通过包括以下步骤的方法制造的: :(1)用硅烷偶联剂对无机颗粒进行表面处理; (2)将经硅烷偶联剂处理的无机颗粒悬浮在含水有机溶剂中,并向悬浮的无机颗粒中添加电解质。发现如此制造的颗粒状无机填充剂可高度分散在由自由基聚合性单体组成的牙科用固化性组合物中,并且该颗粒状无机填充剂可以以较高的填充率填充在牙科用固化性组合物中。

著录项

  • 公开/公告号JP2016193875A

    专利类型

  • 公开/公告日2016-11-17

    原文格式PDF

  • 申请/专利权人 SHOFU INC;

    申请/专利号JP20150084556

  • 发明设计人 FUCHIGAMI KIYOMI;FUJIMURA HIDEFUMI;

    申请日2015-03-31

  • 分类号A61K6/08;A61K6/083;C08F2/44;

  • 国家 JP

  • 入库时间 2022-08-21 13:58:10

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