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Structured iron-based catalyst for producing -olefin from syngas, preparation method and use thereof

机译:一种由合成气制取烯烃的结构化铁基催化剂及其制备方法和用途

摘要

To provide a structured iron-based catalyst for producing -olefin from a synthesis gas, a method for preparing the same and a method of using the same.The catalyst contains the active ingredient iron, an additive and a carrier. The additive comprises a first additive which is a transition metal or a transition metal oxide and a second additive which is a metal oxide. The iron content of the active ingredient is 50.0% to 99.8%, the content of the first additive is 0 to 5.0%, the content of the second additive is 0 to 10%, the other Is the carrier silicon dioxide. The iron precursor of the active ingredient, the precursor of the first additive, and the silicon dioxide of the carrier are made into monodisperse particles using the thermal diffusion method, and then impregnated into the precursor solution of the second additive , A structured iron-based catalyst is obtained. The structured iron-based catalyst is used for producing -olefin from synthesis gas. The monodisperse structured iron-based catalyst has good selectivity because it forms an active center suitable for producing -olefin.(FIG.
机译:为了提供用于从合成气生产烯烃的结构化铁基催化剂,其制备方法和使用该催化剂的方法。催化剂包含活性成分铁,添加剂和载体。添加剂包括为过渡金属或过渡金属氧化物的第一添加剂和为金属氧化物的第二添加剂。活性成分的铁含量为50.0%至99.8%,第一添加剂的含量为0至5.0%,第二添加剂的含量为0至10%,另一种为载体二氧化硅。使用热扩散法将活性成分的铁前驱体,第一添加剂的前驱体和载体的二氧化硅制成单分散颗粒,然后浸渍到第二添加剂的前驱体溶液中,该结构化铁基获得催化剂。结构化铁基催化剂用于从合成气生产α-烯烃。单分散结构的铁基催化剂具有良好的选择性,因为它形成了适合于生产烯烃的活性中心。

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