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Method for producing polyacrylic acid (salt)-based water absorbent resin powder

机译:聚丙烯酸(盐)系吸水性树脂粉末的制造方法

摘要

From a view point of reduction in an out of spec product after surface crosslinking, particularly, when an alkylene carbonate compound is used as a surface crosslinking agent, influence by an air temperature is great, and it is necessary to reduce ethylene glycol which is produced as a byproduct, and there is provided a process for producing a polyacrylic acid (salt)-based water absorbent resin powder, comprisinga step of polymerizing an aqueous acrylic acid (salt)-based monomer solution,a step of drying the resulting polymer,an optional grinding•classifying step, anda surface crosslinking step,wherein in the surface crosslinking step,(1) a surface crosslinking agent containing an alkylene carbonate compound and a polyhydric alcohol compound is mixed into a water absorbent resin powder, the mixture is heat-reacted and, further, simultaneously with, or separately from the mixing, an ion reactive surface crosslinking agent is mixed, and/or(2) mixing treatment of mixing a surface crosslinking agent solution into a water absorbent resin powder containing at least one or more kinds of ion reactive surface crosslinking agents is performed two or more times.
机译:从减少表面交联后的不合格产品的角度来看,特别是当使用碳酸亚烷基酯化合物作为表面交联剂时,受到空气温度的影响很大,并且有必要减少所产生的乙二醇作为副产物,提供了一种制备聚丙烯酸(盐)基吸水性树脂粉末的方法,包括 聚合丙烯酸(盐)基单体水溶液的步骤, 干燥所得聚合物的步骤,< / ListItem> 可选的研磨•分类步骤,以及 表面交联步骤, 其中,在表面交联步骤中, (1)表面将包含碳酸亚烷基酯化合物和多元醇化合物的交联剂混合到吸水性树脂粉末中,对该混合物进行加热反应,并且在混合的同时或分开地混合离子反应性表面交联剂,以及/ or (2)将表面交联剂溶液混合到含有至少一种或多种离子反应性表面交联剂的吸水树脂粉末中的混合处理进行两次或更多次。

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