A method involving polymerizing ethylene in the presence of a catalyst composition containing BaFe12O19 nanoparticles, a zirconocene catalyst, and an alkylaluminoxane co-catalyst. A nanocomposite is formed by the polymerization, whereby the BaFe12O19 nanoparticles are dispersed in a matrix of polyethylene (PE), and the % crystallinity is lowered. The activity of the catalyst is increased in the presence of the BaFe12O19 nanoparticles.
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机译:一种涉及在包含BaFe 12 Sub> O 19 Sub>纳米粒子,锆茂催化剂和烷基铝氧烷助催化剂的催化剂组合物存在下聚合乙烯的方法。通过聚合反应形成纳米复合材料,从而使BaFe 12 Sub> O 19 Sub>纳米颗粒分散在聚乙烯(PE)的基质中,结晶度降低。 BaFe 12 Sub> O 19 Sub>纳米粒子的存在提高了催化剂的活性。
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