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Cathode active material comprising lithium manganese-based oxide and non-aqueous electrolyte secondary battery based upon the same
Cathode active material comprising lithium manganese-based oxide and non-aqueous electrolyte secondary battery based upon the same
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机译:包含锂锰基氧化物和基于其的非水电解质二次电池的阴极活性材料
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摘要
Disclosed is a cathode active material including a lithium manganese-based oxide. The lithium manganese-based oxide has a spinel structure represented by Formula 1 below and high lithium ion diffusivity since (440) planes are predominantly formed in a crystal structure thereof.Li1+xMyMn2-x-yO4-zQz (1);In Formula 1, 0≦x≦0.3, 0≦y≦1, and 0≦z≦1, M includes at least one element selected from the group consisting of Al, Mg, Ni, Co, Fe, Cr, V, Ti, Cu, B, Ca, Zn, Zr, Nb, Mo, Sr, Sb, W, Ti, and Bi, and Q includes at least one element selected from the group consisting of N, F, S, and Cl.
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机译:公开了一种包括锂锰基氧化物的正极活性材料。锂锰基氧化物具有由下式1表示的尖晶石结构并且锂离子扩散率高,因为(440)面主要形成在其晶体结构中。<?in-line-formulae description =“在线公式” end =“ lead”?> Li 1 + x Sub> M y Sub> Mn 2-xy < / Sub> O 4-z Sub> Q z Sub>(1)<?in-line-formulae description =“ In-line Formulae” end =“ tail”?>;在式1、0≤x≤0.3、0≤y≤1和0≤z≤1,M包括选自Al,Mg,Ni,Co,Fe,Cr,V,Ti, Cu,B,Ca,Zn,Zr,Nb,Mo,Sr,Sb,W,Ti和Bi以及Q包括选自由N,F,S和Cl组成的组中的至少一种元素。
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